Bis(tripyrazol-1-ylmethane)nickel(II) tetra­cyanidonickelate(II) dihydrate

The title complex, [Ni(C(10)H(10)N(6))(2)][Ni(CN)(4)]·2H(2)O, contains an octa­hedral nickel(II) cation and a square-planar nickel(II) anion. Both the cation and the anion reside on a crystallographic center of inversion. The Ni(II) center in the cation is coordinated by six pyrazol-1-yl rings of tw...

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Detalles Bibliográficos
Autores principales: Lyubartseva, Ganna, Parkin, Sean
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971905/
https://www.ncbi.nlm.nih.gov/pubmed/21578573
http://dx.doi.org/10.1107/S1600536809046108
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author Lyubartseva, Ganna
Parkin, Sean
author_facet Lyubartseva, Ganna
Parkin, Sean
author_sort Lyubartseva, Ganna
collection PubMed
description The title complex, [Ni(C(10)H(10)N(6))(2)][Ni(CN)(4)]·2H(2)O, contains an octa­hedral nickel(II) cation and a square-planar nickel(II) anion. Both the cation and the anion reside on a crystallographic center of inversion. The Ni(II) center in the cation is coordinated by six pyrazol-1-yl rings of two chelating tripyrazol-1-ylmethane [HC(pz)(3)] ligands, with Ni—N distances that range between 2.0647 (19) and 2.0828 (19) Å. The Ni(II) center in the anion is coordinated by four cyanide ligands, with Ni—C distances in the range 1.869 (2)–1.869 (3) Å. The [Ni(CN)(4)](2−) anions are linked by inversion-related water mol­ecules into extended chains that run parallel to the a axis.
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spelling pubmed-29719052010-12-30 Bis(tripyrazol-1-ylmethane)nickel(II) tetra­cyanidonickelate(II) dihydrate Lyubartseva, Ganna Parkin, Sean Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(C(10)H(10)N(6))(2)][Ni(CN)(4)]·2H(2)O, contains an octa­hedral nickel(II) cation and a square-planar nickel(II) anion. Both the cation and the anion reside on a crystallographic center of inversion. The Ni(II) center in the cation is coordinated by six pyrazol-1-yl rings of two chelating tripyrazol-1-ylmethane [HC(pz)(3)] ligands, with Ni—N distances that range between 2.0647 (19) and 2.0828 (19) Å. The Ni(II) center in the anion is coordinated by four cyanide ligands, with Ni—C distances in the range 1.869 (2)–1.869 (3) Å. The [Ni(CN)(4)](2−) anions are linked by inversion-related water mol­ecules into extended chains that run parallel to the a axis. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971905/ /pubmed/21578573 http://dx.doi.org/10.1107/S1600536809046108 Text en © Lyubartseva and Parkin 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lyubartseva, Ganna
Parkin, Sean
Bis(tripyrazol-1-ylmethane)nickel(II) tetra­cyanidonickelate(II) dihydrate
title Bis(tripyrazol-1-ylmethane)nickel(II) tetra­cyanidonickelate(II) dihydrate
title_full Bis(tripyrazol-1-ylmethane)nickel(II) tetra­cyanidonickelate(II) dihydrate
title_fullStr Bis(tripyrazol-1-ylmethane)nickel(II) tetra­cyanidonickelate(II) dihydrate
title_full_unstemmed Bis(tripyrazol-1-ylmethane)nickel(II) tetra­cyanidonickelate(II) dihydrate
title_short Bis(tripyrazol-1-ylmethane)nickel(II) tetra­cyanidonickelate(II) dihydrate
title_sort bis(tripyrazol-1-ylmethane)nickel(ii) tetra­cyanidonickelate(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971905/
https://www.ncbi.nlm.nih.gov/pubmed/21578573
http://dx.doi.org/10.1107/S1600536809046108
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AT parkinsean bistripyrazol1ylmethanenickeliitetracyanidonickelateiidihydrate

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