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Bis[μ-1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(I) bis(hexafluoridophosphate) acetonitrile disolvate
In the centrosymmetric dinuclear title compound, [Ag(2)(C(36)H(26)N(8))(2)](PF(6))(2)·2C(2)H(3)N, the Ag(+) ion is bound to four N atoms from two 1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine ligands in a distorted tetrahedral geometry. The ligand adopts a twist conformatio...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971906/ https://www.ncbi.nlm.nih.gov/pubmed/21578653 http://dx.doi.org/10.1107/S160053680904882X |
| _version_ | 1782190697660547072 |
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| author | Sun, Qiaozhen Xiao, Tao Chen, Ping Gan, Xiaoqiang Bao, Lin |
| author_facet | Sun, Qiaozhen Xiao, Tao Chen, Ping Gan, Xiaoqiang Bao, Lin |
| author_sort | Sun, Qiaozhen |
| collection | PubMed |
| description | In the centrosymmetric dinuclear title compound, [Ag(2)(C(36)H(26)N(8))(2)](PF(6))(2)·2C(2)H(3)N, the Ag(+) ion is bound to four N atoms from two 1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine ligands in a distorted tetrahedral geometry. The ligand adopts a twist conformation, coordinating two metal centers by three pyridyl N atoms and one imine N atom and spanning two Ag(+) ions, resulting in the formation of a helical dimeric structure. |
| format | Text |
| id | pubmed-2971906 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29719062010-12-30 Bis[μ-1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(I) bis(hexafluoridophosphate) acetonitrile disolvate Sun, Qiaozhen Xiao, Tao Chen, Ping Gan, Xiaoqiang Bao, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Ag(2)(C(36)H(26)N(8))(2)](PF(6))(2)·2C(2)H(3)N, the Ag(+) ion is bound to four N atoms from two 1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine ligands in a distorted tetrahedral geometry. The ligand adopts a twist conformation, coordinating two metal centers by three pyridyl N atoms and one imine N atom and spanning two Ag(+) ions, resulting in the formation of a helical dimeric structure. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971906/ /pubmed/21578653 http://dx.doi.org/10.1107/S160053680904882X Text en © Sun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Sun, Qiaozhen Xiao, Tao Chen, Ping Gan, Xiaoqiang Bao, Lin Bis[μ-1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(I) bis(hexafluoridophosphate) acetonitrile disolvate |
| title | Bis[μ-1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(I) bis(hexafluoridophosphate) acetonitrile disolvate |
| title_full | Bis[μ-1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(I) bis(hexafluoridophosphate) acetonitrile disolvate |
| title_fullStr | Bis[μ-1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(I) bis(hexafluoridophosphate) acetonitrile disolvate |
| title_full_unstemmed | Bis[μ-1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(I) bis(hexafluoridophosphate) acetonitrile disolvate |
| title_short | Bis[μ-1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(I) bis(hexafluoridophosphate) acetonitrile disolvate |
| title_sort | bis[μ-1,2-diphenyl-n,n′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(i) bis(hexafluoridophosphate) acetonitrile disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971906/ https://www.ncbi.nlm.nih.gov/pubmed/21578653 http://dx.doi.org/10.1107/S160053680904882X |
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