Bis[μ(2)-bis­(diphenyl­phosphino)methane]bis­(μ(2)-ethane-1,2-dithiol­ato)-μ(4)-sulfido-μ(2)-sulfido-disulfidodimolybdenum(V)disilver(I) dimethyl­formamide tris­olvate

Treatment of [Et(4)N](2)[(edt)(2)Mo(2)S(2)(μ-S)(2)] (edt = ethane­dithio­l­ate) with two equivalents of Ag(CH(3)CN)(4)ClO(4) in the presence of bis­(diphenyl­phosphino)methane (dppm) ligand gives rise to the title tetra­nuclear cluster, [Ag(2)Mo(2)(C(2)H(4)S(2))(2)S(4)(C(25)H(22)P(2))(2)]·3C(3)H(7)N...

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Detalles Bibliográficos
Autores principales: Wang, Xing-Cong, You, Xiu-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971914/
https://www.ncbi.nlm.nih.gov/pubmed/21578639
http://dx.doi.org/10.1107/S1600536809048648
Descripción
Sumario:Treatment of [Et(4)N](2)[(edt)(2)Mo(2)S(2)(μ-S)(2)] (edt = ethane­dithio­l­ate) with two equivalents of Ag(CH(3)CN)(4)ClO(4) in the presence of bis­(diphenyl­phosphino)methane (dppm) ligand gives rise to the title tetra­nuclear cluster, [Ag(2)Mo(2)(C(2)H(4)S(2))(2)S(4)(C(25)H(22)P(2))(2)]·3C(3)H(7)NO. The complex mol­ecule and one of the dimethyl­formamide (DMF) solvent mol­ecules occupy special positions on a mirror plane. The mol­ecular structure of the complex may be visualized as being built of [Mo(2)S(2)(μ-S)(2)(edt)(2)](2−) dianions and [Ag(2)(dppm)(2)](2+) dications connected by two Ag—μ-S(edt) and two Ag—μ(4)-S bonds.

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