Bis[μ(2)-bis­(diphenyl­phosphino)methane]bis­(μ(2)-ethane-1,2-dithiol­ato)-μ(4)-sulfido-μ(2)-sulfido-disulfidodimolybdenum(V)disilver(I) dimethyl­formamide tris­olvate

Treatment of [Et(4)N](2)[(edt)(2)Mo(2)S(2)(μ-S)(2)] (edt = ethane­dithio­l­ate) with two equivalents of Ag(CH(3)CN)(4)ClO(4) in the presence of bis­(diphenyl­phosphino)methane (dppm) ligand gives rise to the title tetra­nuclear cluster, [Ag(2)Mo(2)(C(2)H(4)S(2))(2)S(4)(C(25)H(22)P(2))(2)]·3C(3)H(7)N...

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Detalles Bibliográficos
Autores principales: Wang, Xing-Cong, You, Xiu-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971914/
https://www.ncbi.nlm.nih.gov/pubmed/21578639
http://dx.doi.org/10.1107/S1600536809048648
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author Wang, Xing-Cong
You, Xiu-Li
author_facet Wang, Xing-Cong
You, Xiu-Li
author_sort Wang, Xing-Cong
collection PubMed
description Treatment of [Et(4)N](2)[(edt)(2)Mo(2)S(2)(μ-S)(2)] (edt = ethane­dithio­l­ate) with two equivalents of Ag(CH(3)CN)(4)ClO(4) in the presence of bis­(diphenyl­phosphino)methane (dppm) ligand gives rise to the title tetra­nuclear cluster, [Ag(2)Mo(2)(C(2)H(4)S(2))(2)S(4)(C(25)H(22)P(2))(2)]·3C(3)H(7)NO. The complex mol­ecule and one of the dimethyl­formamide (DMF) solvent mol­ecules occupy special positions on a mirror plane. The mol­ecular structure of the complex may be visualized as being built of [Mo(2)S(2)(μ-S)(2)(edt)(2)](2−) dianions and [Ag(2)(dppm)(2)](2+) dications connected by two Ag—μ-S(edt) and two Ag—μ(4)-S bonds.
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spelling pubmed-29719142010-12-30 Bis[μ(2)-bis­(diphenyl­phosphino)methane]bis­(μ(2)-ethane-1,2-dithiol­ato)-μ(4)-sulfido-μ(2)-sulfido-disulfidodimolybdenum(V)disilver(I) dimethyl­formamide tris­olvate Wang, Xing-Cong You, Xiu-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Treatment of [Et(4)N](2)[(edt)(2)Mo(2)S(2)(μ-S)(2)] (edt = ethane­dithio­l­ate) with two equivalents of Ag(CH(3)CN)(4)ClO(4) in the presence of bis­(diphenyl­phosphino)methane (dppm) ligand gives rise to the title tetra­nuclear cluster, [Ag(2)Mo(2)(C(2)H(4)S(2))(2)S(4)(C(25)H(22)P(2))(2)]·3C(3)H(7)NO. The complex mol­ecule and one of the dimethyl­formamide (DMF) solvent mol­ecules occupy special positions on a mirror plane. The mol­ecular structure of the complex may be visualized as being built of [Mo(2)S(2)(μ-S)(2)(edt)(2)](2−) dianions and [Ag(2)(dppm)(2)](2+) dications connected by two Ag—μ-S(edt) and two Ag—μ(4)-S bonds. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971914/ /pubmed/21578639 http://dx.doi.org/10.1107/S1600536809048648 Text en © Wang and You 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Xing-Cong
You, Xiu-Li
Bis[μ(2)-bis­(diphenyl­phosphino)methane]bis­(μ(2)-ethane-1,2-dithiol­ato)-μ(4)-sulfido-μ(2)-sulfido-disulfidodimolybdenum(V)disilver(I) dimethyl­formamide tris­olvate
title Bis[μ(2)-bis­(diphenyl­phosphino)methane]bis­(μ(2)-ethane-1,2-dithiol­ato)-μ(4)-sulfido-μ(2)-sulfido-disulfidodimolybdenum(V)disilver(I) dimethyl­formamide tris­olvate
title_full Bis[μ(2)-bis­(diphenyl­phosphino)methane]bis­(μ(2)-ethane-1,2-dithiol­ato)-μ(4)-sulfido-μ(2)-sulfido-disulfidodimolybdenum(V)disilver(I) dimethyl­formamide tris­olvate
title_fullStr Bis[μ(2)-bis­(diphenyl­phosphino)methane]bis­(μ(2)-ethane-1,2-dithiol­ato)-μ(4)-sulfido-μ(2)-sulfido-disulfidodimolybdenum(V)disilver(I) dimethyl­formamide tris­olvate
title_full_unstemmed Bis[μ(2)-bis­(diphenyl­phosphino)methane]bis­(μ(2)-ethane-1,2-dithiol­ato)-μ(4)-sulfido-μ(2)-sulfido-disulfidodimolybdenum(V)disilver(I) dimethyl­formamide tris­olvate
title_short Bis[μ(2)-bis­(diphenyl­phosphino)methane]bis­(μ(2)-ethane-1,2-dithiol­ato)-μ(4)-sulfido-μ(2)-sulfido-disulfidodimolybdenum(V)disilver(I) dimethyl­formamide tris­olvate
title_sort bis[μ(2)-bis­(diphenyl­phosphino)methane]bis­(μ(2)-ethane-1,2-dithiol­ato)-μ(4)-sulfido-μ(2)-sulfido-disulfidodimolybdenum(v)disilver(i) dimethyl­formamide tris­olvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971914/
https://www.ncbi.nlm.nih.gov/pubmed/21578639
http://dx.doi.org/10.1107/S1600536809048648
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AT youxiuli bism2bisdiphenylphosphinomethanebism2ethane12dithiolatom4sulfidom2sulfidodisulfidodimolybdenumvdisilveridimethylformamidetrisolvate

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