Bis(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II) perchlorate

In the cation of the title compound, [CoCl(C(10)H(8)N(2))(2)]ClO(4), the Co(II) atom displays a distorted trigonal-bipyramidal coordination geometry. The two pyridine rings in each 2,2′-bipyridine ligand form dihedral angles of 10.75 (12) and 4.28 (13)°. The crystal packing is stabilized by inter­io...

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Detalles Bibliográficos
Autores principales: Gao, Zhongjun, Li, Fahui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971918/
https://www.ncbi.nlm.nih.gov/pubmed/21578674
http://dx.doi.org/10.1107/S1600536809049034
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author Gao, Zhongjun
Li, Fahui
author_facet Gao, Zhongjun
Li, Fahui
author_sort Gao, Zhongjun
collection PubMed
description In the cation of the title compound, [CoCl(C(10)H(8)N(2))(2)]ClO(4), the Co(II) atom displays a distorted trigonal-bipyramidal coordination geometry. The two pyridine rings in each 2,2′-bipyridine ligand form dihedral angles of 10.75 (12) and 4.28 (13)°. The crystal packing is stabilized by inter­ionic C—H⋯O hydrogen bonds, C—H⋯π inter­actions and aromatic π–π stacking inter­actions, with centroid–centroid distances of 3.616 (7) Å.
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spelling pubmed-29719182010-12-30 Bis(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II) perchlorate Gao, Zhongjun Li, Fahui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [CoCl(C(10)H(8)N(2))(2)]ClO(4), the Co(II) atom displays a distorted trigonal-bipyramidal coordination geometry. The two pyridine rings in each 2,2′-bipyridine ligand form dihedral angles of 10.75 (12) and 4.28 (13)°. The crystal packing is stabilized by inter­ionic C—H⋯O hydrogen bonds, C—H⋯π inter­actions and aromatic π–π stacking inter­actions, with centroid–centroid distances of 3.616 (7) Å. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971918/ /pubmed/21578674 http://dx.doi.org/10.1107/S1600536809049034 Text en © Gao and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Zhongjun
Li, Fahui
Bis(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II) perchlorate
title Bis(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II) perchlorate
title_full Bis(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II) perchlorate
title_fullStr Bis(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II) perchlorate
title_full_unstemmed Bis(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II) perchlorate
title_short Bis(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II) perchlorate
title_sort bis(2,2′-bipyridine-κ(2) n,n′)chloridocobalt(ii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971918/
https://www.ncbi.nlm.nih.gov/pubmed/21578674
http://dx.doi.org/10.1107/S1600536809049034
work_keys_str_mv AT gaozhongjun bis22bipyridinek2nnchloridocobaltiiperchlorate
AT lifahui bis22bipyridinek2nnchloridocobaltiiperchlorate

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