Dichloridobis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)

In the title compound, [HgCl(2)(C(12)H(6)N(2)O(2))(2)], the Hg(II) atom is located on a twofold rotation axis and exists within a distorted octa­hedral geometry defined by a cis-Cl(2)N(4) donor set. Mol­ecules are connected into layers in the ac plane via extensive C—H⋯Cl contacts as each Cl atom fo...

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Detalles Bibliográficos
Autores principales: Figueiras, Carlos A. L., Bomfim, João A. S., Howie, R. Alan, Tiekink, Edward R. T., Wardell, James L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971919/
https://www.ncbi.nlm.nih.gov/pubmed/21578658
http://dx.doi.org/10.1107/S1600536809049289
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author Figueiras, Carlos A. L.
Bomfim, João A. S.
Howie, R. Alan
Tiekink, Edward R. T.
Wardell, James L.
author_facet Figueiras, Carlos A. L.
Bomfim, João A. S.
Howie, R. Alan
Tiekink, Edward R. T.
Wardell, James L.
author_sort Figueiras, Carlos A. L.
collection PubMed
description In the title compound, [HgCl(2)(C(12)H(6)N(2)O(2))(2)], the Hg(II) atom is located on a twofold rotation axis and exists within a distorted octa­hedral geometry defined by a cis-Cl(2)N(4) donor set. Mol­ecules are connected into layers in the ac plane via extensive C—H⋯Cl contacts as each Cl atom forms two such inter­actions. Contacts between the layers are of the type C=O⋯π [O⋯centroid distance = 3.110 (8) Å].
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spelling pubmed-29719192010-12-30 Dichloridobis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II) Figueiras, Carlos A. L. Bomfim, João A. S. Howie, R. Alan Tiekink, Edward R. T. Wardell, James L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [HgCl(2)(C(12)H(6)N(2)O(2))(2)], the Hg(II) atom is located on a twofold rotation axis and exists within a distorted octa­hedral geometry defined by a cis-Cl(2)N(4) donor set. Mol­ecules are connected into layers in the ac plane via extensive C—H⋯Cl contacts as each Cl atom forms two such inter­actions. Contacts between the layers are of the type C=O⋯π [O⋯centroid distance = 3.110 (8) Å]. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971919/ /pubmed/21578658 http://dx.doi.org/10.1107/S1600536809049289 Text en © Figueiras et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Figueiras, Carlos A. L.
Bomfim, João A. S.
Howie, R. Alan
Tiekink, Edward R. T.
Wardell, James L.
Dichloridobis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)
title Dichloridobis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)
title_full Dichloridobis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)
title_fullStr Dichloridobis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)
title_full_unstemmed Dichloridobis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)
title_short Dichloridobis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)
title_sort dichloridobis(1,10-phenanthroline-5,6-dione-κ(2) n,n′)mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971919/
https://www.ncbi.nlm.nih.gov/pubmed/21578658
http://dx.doi.org/10.1107/S1600536809049289
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