catena-Poly[[(6,7,9,10,17,18,20,21-octa­hydro-5,8,11,16,19,22-hexa­oxadibenzo[a,j]cyclo­octa­decene)barium]-di-μ-thio­cyanato-[thio­cyanato­diaurate(I)(Au—Au)]-μ-thio­cyanato]

In the title compound, [Au(2)Ba(NCS)(4)(C(20)H(24)O(6))](n), the dithio­­cyanato­aurate(I) anion adopts a dimeric structure with an Au⋯Au distance of 3.1109 (10) Å; both Au(I) atoms are also bonded to two S atoms. The Ba(II) ion adopts an irregular BaN(3)O(6) geometry, arising from the crown ether a...

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Detalles Bibliográficos
Autores principales: Stroud, Tonia L., Coker, Nathan L., Krause, Jeanette A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971920/
https://www.ncbi.nlm.nih.gov/pubmed/21578559
http://dx.doi.org/10.1107/S1600536809045218
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author Stroud, Tonia L.
Coker, Nathan L.
Krause, Jeanette A.
author_facet Stroud, Tonia L.
Coker, Nathan L.
Krause, Jeanette A.
author_sort Stroud, Tonia L.
collection PubMed
description In the title compound, [Au(2)Ba(NCS)(4)(C(20)H(24)O(6))](n), the dithio­­cyanato­aurate(I) anion adopts a dimeric structure with an Au⋯Au distance of 3.1109 (10) Å; both Au(I) atoms are also bonded to two S atoms. The Ba(II) ion adopts an irregular BaN(3)O(6) geometry, arising from the crown ether and three adjacent thio­cyanate N atoms; the extended structure of the complex can be described as a one-dimensional coordination polymer generated by the Ba⋯N inter­actions (two on the endo side and one on the exo side of the crown ether) running parallel to the b axis, with an anti­parallel arrangement of ribbons in the unit cell.
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spelling pubmed-29719202010-12-30 catena-Poly[[(6,7,9,10,17,18,20,21-octa­hydro-5,8,11,16,19,22-hexa­oxadibenzo[a,j]cyclo­octa­decene)barium]-di-μ-thio­cyanato-[thio­cyanato­diaurate(I)(Au—Au)]-μ-thio­cyanato] Stroud, Tonia L. Coker, Nathan L. Krause, Jeanette A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Au(2)Ba(NCS)(4)(C(20)H(24)O(6))](n), the dithio­­cyanato­aurate(I) anion adopts a dimeric structure with an Au⋯Au distance of 3.1109 (10) Å; both Au(I) atoms are also bonded to two S atoms. The Ba(II) ion adopts an irregular BaN(3)O(6) geometry, arising from the crown ether and three adjacent thio­cyanate N atoms; the extended structure of the complex can be described as a one-dimensional coordination polymer generated by the Ba⋯N inter­actions (two on the endo side and one on the exo side of the crown ether) running parallel to the b axis, with an anti­parallel arrangement of ribbons in the unit cell. International Union of Crystallography 2009-11-04 /pmc/articles/PMC2971920/ /pubmed/21578559 http://dx.doi.org/10.1107/S1600536809045218 Text en © Stroud et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Stroud, Tonia L.
Coker, Nathan L.
Krause, Jeanette A.
catena-Poly[[(6,7,9,10,17,18,20,21-octa­hydro-5,8,11,16,19,22-hexa­oxadibenzo[a,j]cyclo­octa­decene)barium]-di-μ-thio­cyanato-[thio­cyanato­diaurate(I)(Au—Au)]-μ-thio­cyanato]
title catena-Poly[[(6,7,9,10,17,18,20,21-octa­hydro-5,8,11,16,19,22-hexa­oxadibenzo[a,j]cyclo­octa­decene)barium]-di-μ-thio­cyanato-[thio­cyanato­diaurate(I)(Au—Au)]-μ-thio­cyanato]
title_full catena-Poly[[(6,7,9,10,17,18,20,21-octa­hydro-5,8,11,16,19,22-hexa­oxadibenzo[a,j]cyclo­octa­decene)barium]-di-μ-thio­cyanato-[thio­cyanato­diaurate(I)(Au—Au)]-μ-thio­cyanato]
title_fullStr catena-Poly[[(6,7,9,10,17,18,20,21-octa­hydro-5,8,11,16,19,22-hexa­oxadibenzo[a,j]cyclo­octa­decene)barium]-di-μ-thio­cyanato-[thio­cyanato­diaurate(I)(Au—Au)]-μ-thio­cyanato]
title_full_unstemmed catena-Poly[[(6,7,9,10,17,18,20,21-octa­hydro-5,8,11,16,19,22-hexa­oxadibenzo[a,j]cyclo­octa­decene)barium]-di-μ-thio­cyanato-[thio­cyanato­diaurate(I)(Au—Au)]-μ-thio­cyanato]
title_short catena-Poly[[(6,7,9,10,17,18,20,21-octa­hydro-5,8,11,16,19,22-hexa­oxadibenzo[a,j]cyclo­octa­decene)barium]-di-μ-thio­cyanato-[thio­cyanato­diaurate(I)(Au—Au)]-μ-thio­cyanato]
title_sort catena-poly[[(6,7,9,10,17,18,20,21-octa­hydro-5,8,11,16,19,22-hexa­oxadibenzo[a,j]cyclo­octa­decene)barium]-di-μ-thio­cyanato-[thio­cyanato­diaurate(i)(au—au)]-μ-thio­cyanato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971920/
https://www.ncbi.nlm.nih.gov/pubmed/21578559
http://dx.doi.org/10.1107/S1600536809045218
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