Di-μ-iodido-bis­[acet­yl(4-methyl-2,6,7-trioxa-1-phosphabicyclo­[2.2.2]octa­ne)(N-nitroso-N-oxidoaniline-κ(2) O,O′)rhodium(III)]

The title compound, [Rh(2)(C(6)H(5)N(2)O(2))(2)(C(2)H(3)O)(2)I(2)(C(5)H(9)O(3)P)(2)], contains a binuclear centrosymmetric Rh(III) dimer bridged by iodide anions, with respective Rh⋯Rh and I⋯I distances of 4.1437 (5) and 3.9144 (5) Å. The Rh(III) atom is in a distorted octa­hedral RhCI(2)O(2)P coord...

Descripción completa

Detalles Bibliográficos
Autores principales: Venter, Johan A., Purcell, W., Visser, H. G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971923/
https://www.ncbi.nlm.nih.gov/pubmed/21578572
http://dx.doi.org/10.1107/S1600536809043050
_version_ 1782190701711196160
author Venter, Johan A.
Purcell, W.
Visser, H. G.
author_facet Venter, Johan A.
Purcell, W.
Visser, H. G.
author_sort Venter, Johan A.
collection PubMed
description The title compound, [Rh(2)(C(6)H(5)N(2)O(2))(2)(C(2)H(3)O)(2)I(2)(C(5)H(9)O(3)P)(2)], contains a binuclear centrosymmetric Rh(III) dimer bridged by iodide anions, with respective Rh⋯Rh and I⋯I distances of 4.1437 (5) and 3.9144 (5) Å. The Rh(III) atom is in a distorted octa­hedral RhCI(2)O(2)P coordination with considerably different Rh—I distances to the bridging iodide anions. There are no classical hydrogen-bonding inter­actions observed for this complex.
format Text
id pubmed-2971923
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29719232010-12-30 Di-μ-iodido-bis­[acet­yl(4-methyl-2,6,7-trioxa-1-phosphabicyclo­[2.2.2]octa­ne)(N-nitroso-N-oxidoaniline-κ(2) O,O′)rhodium(III)] Venter, Johan A. Purcell, W. Visser, H. G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Rh(2)(C(6)H(5)N(2)O(2))(2)(C(2)H(3)O)(2)I(2)(C(5)H(9)O(3)P)(2)], contains a binuclear centrosymmetric Rh(III) dimer bridged by iodide anions, with respective Rh⋯Rh and I⋯I distances of 4.1437 (5) and 3.9144 (5) Å. The Rh(III) atom is in a distorted octa­hedral RhCI(2)O(2)P coordination with considerably different Rh—I distances to the bridging iodide anions. There are no classical hydrogen-bonding inter­actions observed for this complex. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971923/ /pubmed/21578572 http://dx.doi.org/10.1107/S1600536809043050 Text en © Venter et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Venter, Johan A.
Purcell, W.
Visser, H. G.
Di-μ-iodido-bis­[acet­yl(4-methyl-2,6,7-trioxa-1-phosphabicyclo­[2.2.2]octa­ne)(N-nitroso-N-oxidoaniline-κ(2) O,O′)rhodium(III)]
title Di-μ-iodido-bis­[acet­yl(4-methyl-2,6,7-trioxa-1-phosphabicyclo­[2.2.2]octa­ne)(N-nitroso-N-oxidoaniline-κ(2) O,O′)rhodium(III)]
title_full Di-μ-iodido-bis­[acet­yl(4-methyl-2,6,7-trioxa-1-phosphabicyclo­[2.2.2]octa­ne)(N-nitroso-N-oxidoaniline-κ(2) O,O′)rhodium(III)]
title_fullStr Di-μ-iodido-bis­[acet­yl(4-methyl-2,6,7-trioxa-1-phosphabicyclo­[2.2.2]octa­ne)(N-nitroso-N-oxidoaniline-κ(2) O,O′)rhodium(III)]
title_full_unstemmed Di-μ-iodido-bis­[acet­yl(4-methyl-2,6,7-trioxa-1-phosphabicyclo­[2.2.2]octa­ne)(N-nitroso-N-oxidoaniline-κ(2) O,O′)rhodium(III)]
title_short Di-μ-iodido-bis­[acet­yl(4-methyl-2,6,7-trioxa-1-phosphabicyclo­[2.2.2]octa­ne)(N-nitroso-N-oxidoaniline-κ(2) O,O′)rhodium(III)]
title_sort di-μ-iodido-bis­[acet­yl(4-methyl-2,6,7-trioxa-1-phosphabicyclo­[2.2.2]octa­ne)(n-nitroso-n-oxidoaniline-κ(2) o,o′)rhodium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971923/
https://www.ncbi.nlm.nih.gov/pubmed/21578572
http://dx.doi.org/10.1107/S1600536809043050
work_keys_str_mv AT venterjohana dimiodidobisacetyl4methyl267trioxa1phosphabicyclo222octanennitrosonoxidoanilinek2oorhodiumiii
AT purcellw dimiodidobisacetyl4methyl267trioxa1phosphabicyclo222octanennitrosonoxidoanilinek2oorhodiumiii
AT visserhg dimiodidobisacetyl4methyl267trioxa1phosphabicyclo222octanennitrosonoxidoanilinek2oorhodiumiii

Ejemplares similares