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Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-[tris(4-methylphenyl)arsine-1κAs]-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)As)(CO)(11)], one equatorial carbonyl group has been substituted by the monodentate arsine ligand, leaving one equatorial and two axial carbonyl substituents on the Ru atom. The remaining two Ru atoms each carry two equatorial and two ax...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971926/ https://www.ncbi.nlm.nih.gov/pubmed/21578645 http://dx.doi.org/10.1107/S1600536809046935 |
| _version_ | 1782190702424227840 |
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| author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
| author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
| author_sort | Shawkataly, Omar bin |
| collection | PubMed |
| description | In the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)As)(CO)(11)], one equatorial carbonyl group has been substituted by the monodentate arsine ligand, leaving one equatorial and two axial carbonyl substituents on the Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. The three arsine-substituted phenyl rings make dihedral angles of 73.2 (2), 71.0 (2) and 75.3 (2)° with each other. In the crystal packing, molecules are stacked down the b axis and each molecule is stabilized by an intramolecular C—H⋯O hydrogen bond. |
| format | Text |
| id | pubmed-2971926 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29719262010-12-30 Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-[tris(4-methylphenyl)arsine-1κAs]-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)As)(CO)(11)], one equatorial carbonyl group has been substituted by the monodentate arsine ligand, leaving one equatorial and two axial carbonyl substituents on the Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. The three arsine-substituted phenyl rings make dihedral angles of 73.2 (2), 71.0 (2) and 75.3 (2)° with each other. In the crystal packing, molecules are stacked down the b axis and each molecule is stabilized by an intramolecular C—H⋯O hydrogen bond. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971926/ /pubmed/21578645 http://dx.doi.org/10.1107/S1600536809046935 Text en © Shawkataly et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-[tris(4-methylphenyl)arsine-1κAs]-triangulo-triruthenium(0) |
| title | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(4-methylphenyl)arsine-1κAs]-triangulo-triruthenium(0) |
| title_full | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(4-methylphenyl)arsine-1κAs]-triangulo-triruthenium(0) |
| title_fullStr | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(4-methylphenyl)arsine-1κAs]-triangulo-triruthenium(0) |
| title_full_unstemmed | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(4-methylphenyl)arsine-1κAs]-triangulo-triruthenium(0) |
| title_short | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-[tris(4-methylphenyl)arsine-1κAs]-triangulo-triruthenium(0) |
| title_sort | undecacarbonyl-1κ(3)
c,2κ(4)
c,3κ(4)
c-[tris(4-methylphenyl)arsine-1κas]-triangulo-triruthenium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971926/ https://www.ncbi.nlm.nih.gov/pubmed/21578645 http://dx.doi.org/10.1107/S1600536809046935 |
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