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catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzo­ato-κ(2) O:O′]

In the title compound, [Zn(C(14)H(8)O(5))(C(15)H(11)N(3))](n), both the Zn(II) ion and the oxydibenzoate ligand are located on a twofold rotation axis. The Zn(II) centre is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand and two O atoms from two 2,2′-oxydibenzoate ligand...

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Detalles Bibliográficos
Autores principales: Gong, Hai-Yan, Bai, Yan, Liu, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971933/
https://www.ncbi.nlm.nih.gov/pubmed/21578619
http://dx.doi.org/10.1107/S1600536809047679
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author Gong, Hai-Yan
Bai, Yan
Liu, Wei
author_facet Gong, Hai-Yan
Bai, Yan
Liu, Wei
author_sort Gong, Hai-Yan
collection PubMed
description In the title compound, [Zn(C(14)H(8)O(5))(C(15)H(11)N(3))](n), both the Zn(II) ion and the oxydibenzoate ligand are located on a twofold rotation axis. The Zn(II) centre is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand and two O atoms from two 2,2′-oxydibenzoate ligands, forming a distorted trigonal-bipyramidal coordination environment. Further coordination via the 2,2′-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. Aromatic π–π stacking inter­actions are observed between adjacent terpyridine ligands with a centroid–centroid distance of 3.568 (2) Å.
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spelling pubmed-29719332010-12-30 catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzo­ato-κ(2) O:O′] Gong, Hai-Yan Bai, Yan Liu, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(14)H(8)O(5))(C(15)H(11)N(3))](n), both the Zn(II) ion and the oxydibenzoate ligand are located on a twofold rotation axis. The Zn(II) centre is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand and two O atoms from two 2,2′-oxydibenzoate ligands, forming a distorted trigonal-bipyramidal coordination environment. Further coordination via the 2,2′-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. Aromatic π–π stacking inter­actions are observed between adjacent terpyridine ligands with a centroid–centroid distance of 3.568 (2) Å. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971933/ /pubmed/21578619 http://dx.doi.org/10.1107/S1600536809047679 Text en © Gong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gong, Hai-Yan
Bai, Yan
Liu, Wei
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzo­ato-κ(2) O:O′]
title catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzo­ato-κ(2) O:O′]
title_full catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzo­ato-κ(2) O:O′]
title_fullStr catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzo­ato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzo­ato-κ(2) O:O′]
title_short catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzo­ato-κ(2) O:O′]
title_sort catena-poly[[(2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)zinc(ii)]-μ-2,2′-oxydibenzo­ato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971933/
https://www.ncbi.nlm.nih.gov/pubmed/21578619
http://dx.doi.org/10.1107/S1600536809047679
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