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catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′]
In the title compound, [Zn(C(14)H(8)O(5))(C(15)H(11)N(3))](n), both the Zn(II) ion and the oxydibenzoate ligand are located on a twofold rotation axis. The Zn(II) centre is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand and two O atoms from two 2,2′-oxydibenzoate ligand...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971933/ https://www.ncbi.nlm.nih.gov/pubmed/21578619 http://dx.doi.org/10.1107/S1600536809047679 |
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author | Gong, Hai-Yan Bai, Yan Liu, Wei |
author_facet | Gong, Hai-Yan Bai, Yan Liu, Wei |
author_sort | Gong, Hai-Yan |
collection | PubMed |
description | In the title compound, [Zn(C(14)H(8)O(5))(C(15)H(11)N(3))](n), both the Zn(II) ion and the oxydibenzoate ligand are located on a twofold rotation axis. The Zn(II) centre is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand and two O atoms from two 2,2′-oxydibenzoate ligands, forming a distorted trigonal-bipyramidal coordination environment. Further coordination via the 2,2′-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. Aromatic π–π stacking interactions are observed between adjacent terpyridine ligands with a centroid–centroid distance of 3.568 (2) Å. |
format | Text |
id | pubmed-2971933 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29719332010-12-30 catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′] Gong, Hai-Yan Bai, Yan Liu, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(14)H(8)O(5))(C(15)H(11)N(3))](n), both the Zn(II) ion and the oxydibenzoate ligand are located on a twofold rotation axis. The Zn(II) centre is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand and two O atoms from two 2,2′-oxydibenzoate ligands, forming a distorted trigonal-bipyramidal coordination environment. Further coordination via the 2,2′-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. Aromatic π–π stacking interactions are observed between adjacent terpyridine ligands with a centroid–centroid distance of 3.568 (2) Å. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971933/ /pubmed/21578619 http://dx.doi.org/10.1107/S1600536809047679 Text en © Gong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gong, Hai-Yan Bai, Yan Liu, Wei catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ(2) O:O′] |
title |
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ(2)
O:O′] |
title_full |
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ(2)
O:O′] |
title_fullStr |
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ(2)
O:O′] |
title_full_unstemmed |
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ(2)
O:O′] |
title_short |
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ(2)
O:O′] |
title_sort | catena-poly[[(2,2′:6′,2′′-terpyridine-κ(3)
n,n′,n′′)zinc(ii)]-μ-2,2′-oxydibenzoato-κ(2)
o:o′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971933/ https://www.ncbi.nlm.nih.gov/pubmed/21578619 http://dx.doi.org/10.1107/S1600536809047679 |
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