catena-Poly[[[aqua­silver(I)]-μ-1,1′-(butane-1,4-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)] hemi(biphenyl-4,4′-dicarboxyl­ate) dihydrate]

In the title compound, {[Ag(C(10)H(14)N(4))(H(2)O)](C(14)H(8)O(4))(0.5)·2H(2)O}(n), the Ag(I) ion is three-coordinated by two N atoms from two independent 1,1′-(butane-1,4-di­yl)di-1H-imidazole (BBI) ligands and one water O atom in a distorted T-shaped coordination geometry. The biphenyl-4,4′-dicarb...

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Detalles Bibliográficos
Autor principal: Zhang, Zheyu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971936/
https://www.ncbi.nlm.nih.gov/pubmed/21578566
http://dx.doi.org/10.1107/S1600536809045826
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author Zhang, Zheyu
author_facet Zhang, Zheyu
author_sort Zhang, Zheyu
collection PubMed
description In the title compound, {[Ag(C(10)H(14)N(4))(H(2)O)](C(14)H(8)O(4))(0.5)·2H(2)O}(n), the Ag(I) ion is three-coordinated by two N atoms from two independent 1,1′-(butane-1,4-di­yl)di-1H-imidazole (BBI) ligands and one water O atom in a distorted T-shaped coordination geometry. The biphenyl-4,4′-dicarboxyl­ate (BPDC) dianions do not coordinate to Ag(I) ions but act as counter-ions. The Ag(I) ions are linked by BBI ligands, forming a zigzag chain. These chains are linked into a two-dimensional supra­molecular architecture by O—H⋯O hydrogen-bonding inter­actions between water mol­ecules and carboxyl­ate O atoms of the BPDC dianions.
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spelling pubmed-29719362010-12-30 catena-Poly[[[aqua­silver(I)]-μ-1,1′-(butane-1,4-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)] hemi(biphenyl-4,4′-dicarboxyl­ate) dihydrate] Zhang, Zheyu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Ag(C(10)H(14)N(4))(H(2)O)](C(14)H(8)O(4))(0.5)·2H(2)O}(n), the Ag(I) ion is three-coordinated by two N atoms from two independent 1,1′-(butane-1,4-di­yl)di-1H-imidazole (BBI) ligands and one water O atom in a distorted T-shaped coordination geometry. The biphenyl-4,4′-dicarboxyl­ate (BPDC) dianions do not coordinate to Ag(I) ions but act as counter-ions. The Ag(I) ions are linked by BBI ligands, forming a zigzag chain. These chains are linked into a two-dimensional supra­molecular architecture by O—H⋯O hydrogen-bonding inter­actions between water mol­ecules and carboxyl­ate O atoms of the BPDC dianions. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971936/ /pubmed/21578566 http://dx.doi.org/10.1107/S1600536809045826 Text en © Zheyu Zhang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Zheyu
catena-Poly[[[aqua­silver(I)]-μ-1,1′-(butane-1,4-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)] hemi(biphenyl-4,4′-dicarboxyl­ate) dihydrate]
title catena-Poly[[[aqua­silver(I)]-μ-1,1′-(butane-1,4-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)] hemi(biphenyl-4,4′-dicarboxyl­ate) dihydrate]
title_full catena-Poly[[[aqua­silver(I)]-μ-1,1′-(butane-1,4-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)] hemi(biphenyl-4,4′-dicarboxyl­ate) dihydrate]
title_fullStr catena-Poly[[[aqua­silver(I)]-μ-1,1′-(butane-1,4-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)] hemi(biphenyl-4,4′-dicarboxyl­ate) dihydrate]
title_full_unstemmed catena-Poly[[[aqua­silver(I)]-μ-1,1′-(butane-1,4-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)] hemi(biphenyl-4,4′-dicarboxyl­ate) dihydrate]
title_short catena-Poly[[[aqua­silver(I)]-μ-1,1′-(butane-1,4-di­yl)di-1H-imidazole-κ(2) N (3):N (3′)] hemi(biphenyl-4,4′-dicarboxyl­ate) dihydrate]
title_sort catena-poly[[[aqua­silver(i)]-μ-1,1′-(butane-1,4-di­yl)di-1h-imidazole-κ(2) n (3):n (3′)] hemi(biphenyl-4,4′-dicarboxyl­ate) dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971936/
https://www.ncbi.nlm.nih.gov/pubmed/21578566
http://dx.doi.org/10.1107/S1600536809045826
work_keys_str_mv AT zhangzheyu catenapolyaquasilverim11butane14diyldi1himidazolek2n3n3hemibiphenyl44dicarboxylatedihydrate

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