Aqua­{6,6-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}copper(II) acetonitrile solvate

In the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)]·C(2)H(3)N, the Cu(II) ion is coordinated by two N and two O atoms from the tetra­dentate Schiff base ligand, which contains a propyl­ene fragment disordered over two conformations in a 0.64 (1):0.36 (1) ratio, and one O atom from the water mol­e...

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Detalles Bibliográficos
Autor principal: Wang, Xinfang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971939/
https://www.ncbi.nlm.nih.gov/pubmed/21578669
http://dx.doi.org/10.1107/S1600536809049137
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author Wang, Xinfang
author_facet Wang, Xinfang
author_sort Wang, Xinfang
collection PubMed
description In the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)]·C(2)H(3)N, the Cu(II) ion is coordinated by two N and two O atoms from the tetra­dentate Schiff base ligand, which contains a propyl­ene fragment disordered over two conformations in a 0.64 (1):0.36 (1) ratio, and one O atom from the water mol­ecule in a distorted square-pyramidal geometry. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into chains along the a axis.
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spelling pubmed-29719392010-12-30 Aqua­{6,6-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}copper(II) acetonitrile solvate Wang, Xinfang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)]·C(2)H(3)N, the Cu(II) ion is coordinated by two N and two O atoms from the tetra­dentate Schiff base ligand, which contains a propyl­ene fragment disordered over two conformations in a 0.64 (1):0.36 (1) ratio, and one O atom from the water mol­ecule in a distorted square-pyramidal geometry. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into chains along the a axis. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971939/ /pubmed/21578669 http://dx.doi.org/10.1107/S1600536809049137 Text en © Xinfang Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Xinfang
Aqua­{6,6-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}copper(II) acetonitrile solvate
title Aqua­{6,6-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}copper(II) acetonitrile solvate
title_full Aqua­{6,6-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}copper(II) acetonitrile solvate
title_fullStr Aqua­{6,6-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}copper(II) acetonitrile solvate
title_full_unstemmed Aqua­{6,6-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}copper(II) acetonitrile solvate
title_short Aqua­{6,6-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) O,N,N′,O′}copper(II) acetonitrile solvate
title_sort aqua­{6,6-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(4) o,n,n′,o′}copper(ii) acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971939/
https://www.ncbi.nlm.nih.gov/pubmed/21578669
http://dx.doi.org/10.1107/S1600536809049137
work_keys_str_mv AT wangxinfang aqua66dimethoxy22propane13diylbisnitrilomethylidynediphenolatok4onnocopperiiacetonitrilesolvate

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