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catena-Poly[[[bis­(N,N-dimethyl­formamide)iron(II)]-{μ-2,2′-bis­(diphenyl­phosphino­yl)-N,N′-[(1R,2R)-cyclo­hexane-1,2-di­yl]dibenzamide}] bis­(perchlorate) N,N-dimethyl­formamide disolvate]

The title extended solid coordination compound, {[Fe(C(44)H(40)N(2)O(4)P(2))(C(3)H(7)NO)(2)](ClO(4))(2)·2C(3)H(7)NO}(n), was crystallized un­ex­pectedly from the reaction mixture containing the Trost ligand (1R,2R)-(+)-1,2-diamino­cyclo­hexane-N,N′-bis­(2′-di­phenyl­phosphinobenzo­yl) and Fe(ClO(4))...

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Detalles Bibliográficos
Autores principales: Ferrell, Grant R., Moore, Curtis, Rheingold, Arnold L., Daley, Christopher J. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971940/
https://www.ncbi.nlm.nih.gov/pubmed/21578561
http://dx.doi.org/10.1107/S1600536809045188
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author Ferrell, Grant R.
Moore, Curtis
Rheingold, Arnold L.
Daley, Christopher J. A.
author_facet Ferrell, Grant R.
Moore, Curtis
Rheingold, Arnold L.
Daley, Christopher J. A.
author_sort Ferrell, Grant R.
collection PubMed
description The title extended solid coordination compound, {[Fe(C(44)H(40)N(2)O(4)P(2))(C(3)H(7)NO)(2)](ClO(4))(2)·2C(3)H(7)NO}(n), was crystallized un­ex­pectedly from the reaction mixture containing the Trost ligand (1R,2R)-(+)-1,2-diamino­cyclo­hexane-N,N′-bis­(2′-di­phenyl­phosphinobenzo­yl) and Fe(ClO(4))(2)·6H(2)O in a 1:1 ratio in dimethyl­formamide (DMF) under reflux conditions. The polymeric complex is characterized by Fe(II) metal centers that are coordinated by two oxidized Trost ligands, each coordinated in a bidentate fashion in a square plane, along with two DMF mol­ecules above and below the plane [average Fe—O(DMF) = 2.086 (4) Å], forming an overall pseudo-octa­hedral geometry. The Trost ligand binds adjacent Fe(II) centers, each Fe(II) being bound through the O atom of one of the phosphine oxides [average Fe—O(PPh2) = 2.115 (4) Å] and the carbonyl O atom of the adjacent amide [average Fe—O(amide) = 2.192 (3) Å]. Disorder is observed in the co-solvated solvent: there are two DMF mol­ecules per Fe(II) centre, which were modeled as one DMF mol­ecule with complete occupancy and the other being modeled in two positions with equal occupancy. Disorder was also observed with one of the perchlorate anions, which was modeled in two positions with 0.75:0.25 occupancy.
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spelling pubmed-29719402010-12-30 catena-Poly[[[bis­(N,N-dimethyl­formamide)iron(II)]-{μ-2,2′-bis­(diphenyl­phosphino­yl)-N,N′-[(1R,2R)-cyclo­hexane-1,2-di­yl]dibenzamide}] bis­(perchlorate) N,N-dimethyl­formamide disolvate] Ferrell, Grant R. Moore, Curtis Rheingold, Arnold L. Daley, Christopher J. A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title extended solid coordination compound, {[Fe(C(44)H(40)N(2)O(4)P(2))(C(3)H(7)NO)(2)](ClO(4))(2)·2C(3)H(7)NO}(n), was crystallized un­ex­pectedly from the reaction mixture containing the Trost ligand (1R,2R)-(+)-1,2-diamino­cyclo­hexane-N,N′-bis­(2′-di­phenyl­phosphinobenzo­yl) and Fe(ClO(4))(2)·6H(2)O in a 1:1 ratio in dimethyl­formamide (DMF) under reflux conditions. The polymeric complex is characterized by Fe(II) metal centers that are coordinated by two oxidized Trost ligands, each coordinated in a bidentate fashion in a square plane, along with two DMF mol­ecules above and below the plane [average Fe—O(DMF) = 2.086 (4) Å], forming an overall pseudo-octa­hedral geometry. The Trost ligand binds adjacent Fe(II) centers, each Fe(II) being bound through the O atom of one of the phosphine oxides [average Fe—O(PPh2) = 2.115 (4) Å] and the carbonyl O atom of the adjacent amide [average Fe—O(amide) = 2.192 (3) Å]. Disorder is observed in the co-solvated solvent: there are two DMF mol­ecules per Fe(II) centre, which were modeled as one DMF mol­ecule with complete occupancy and the other being modeled in two positions with equal occupancy. Disorder was also observed with one of the perchlorate anions, which was modeled in two positions with 0.75:0.25 occupancy. International Union of Crystallography 2009-11-04 /pmc/articles/PMC2971940/ /pubmed/21578561 http://dx.doi.org/10.1107/S1600536809045188 Text en © Ferrell et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ferrell, Grant R.
Moore, Curtis
Rheingold, Arnold L.
Daley, Christopher J. A.
catena-Poly[[[bis­(N,N-dimethyl­formamide)iron(II)]-{μ-2,2′-bis­(diphenyl­phosphino­yl)-N,N′-[(1R,2R)-cyclo­hexane-1,2-di­yl]dibenzamide}] bis­(perchlorate) N,N-dimethyl­formamide disolvate]
title catena-Poly[[[bis­(N,N-dimethyl­formamide)iron(II)]-{μ-2,2′-bis­(diphenyl­phosphino­yl)-N,N′-[(1R,2R)-cyclo­hexane-1,2-di­yl]dibenzamide}] bis­(perchlorate) N,N-dimethyl­formamide disolvate]
title_full catena-Poly[[[bis­(N,N-dimethyl­formamide)iron(II)]-{μ-2,2′-bis­(diphenyl­phosphino­yl)-N,N′-[(1R,2R)-cyclo­hexane-1,2-di­yl]dibenzamide}] bis­(perchlorate) N,N-dimethyl­formamide disolvate]
title_fullStr catena-Poly[[[bis­(N,N-dimethyl­formamide)iron(II)]-{μ-2,2′-bis­(diphenyl­phosphino­yl)-N,N′-[(1R,2R)-cyclo­hexane-1,2-di­yl]dibenzamide}] bis­(perchlorate) N,N-dimethyl­formamide disolvate]
title_full_unstemmed catena-Poly[[[bis­(N,N-dimethyl­formamide)iron(II)]-{μ-2,2′-bis­(diphenyl­phosphino­yl)-N,N′-[(1R,2R)-cyclo­hexane-1,2-di­yl]dibenzamide}] bis­(perchlorate) N,N-dimethyl­formamide disolvate]
title_short catena-Poly[[[bis­(N,N-dimethyl­formamide)iron(II)]-{μ-2,2′-bis­(diphenyl­phosphino­yl)-N,N′-[(1R,2R)-cyclo­hexane-1,2-di­yl]dibenzamide}] bis­(perchlorate) N,N-dimethyl­formamide disolvate]
title_sort catena-poly[[[bis­(n,n-dimethyl­formamide)iron(ii)]-{μ-2,2′-bis­(diphenyl­phosphino­yl)-n,n′-[(1r,2r)-cyclo­hexane-1,2-di­yl]dibenzamide}] bis­(perchlorate) n,n-dimethyl­formamide disolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971940/
https://www.ncbi.nlm.nih.gov/pubmed/21578561
http://dx.doi.org/10.1107/S1600536809045188
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