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Tetra­kis[μ-4-(dimethyl­amino)benzoato-κ(2) O:O′]bis­[(N,N-diethyl­nicotinamide-κN (1))zinc(II)]

The title mol­ecule, [Zn(2)(C(9)H(10)NO(2))(4)(C(10)H(14)N(2)O)(2)], is a centrosymmetric binuclear complex, with Zn atoms [Zn⋯Zn′ = 2.8927 (4) Å] bridged by four carboxyl­ate groups from the dimethyl­amino­benzoate (DMAB) ligands. The four carboxyl O atoms around the Zn atom form a distorted square...

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Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Aybirdi, Özgür, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971944/
https://www.ncbi.nlm.nih.gov/pubmed/21578613
http://dx.doi.org/10.1107/S1600536809047473
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author Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description The title mol­ecule, [Zn(2)(C(9)H(10)NO(2))(4)(C(10)H(14)N(2)O)(2)], is a centrosymmetric binuclear complex, with Zn atoms [Zn⋯Zn′ = 2.8927 (4) Å] bridged by four carboxyl­ate groups from the dimethyl­amino­benzoate (DMAB) ligands. The four carboxyl O atoms around the Zn atom form a distorted square-planar arrangement; the distorted square-pyramidal coordination geometry is completed by the pyridine N atom of the N,N-diethyl­nicotinamide (DENA) ligand. The Zn atom is displaced by 0.3326 (2) Å from the plane of the four O atoms, with an average Zn—O distance of 2.0416 (12) Å. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 5.31 (8) and 11.00 (9)°, while the pyridine ring is oriented at dihedral angles of 66.26 (6) and 37.88 (7)° with respect to the benzene rings. Weak intra­molecular C—H⋯O and inter­molecular C—H⋯π inter­actions are present.
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spelling pubmed-29719442010-12-30 Tetra­kis[μ-4-(dimethyl­amino)benzoato-κ(2) O:O′]bis­[(N,N-diethyl­nicotinamide-κN (1))zinc(II)] Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mol­ecule, [Zn(2)(C(9)H(10)NO(2))(4)(C(10)H(14)N(2)O)(2)], is a centrosymmetric binuclear complex, with Zn atoms [Zn⋯Zn′ = 2.8927 (4) Å] bridged by four carboxyl­ate groups from the dimethyl­amino­benzoate (DMAB) ligands. The four carboxyl O atoms around the Zn atom form a distorted square-planar arrangement; the distorted square-pyramidal coordination geometry is completed by the pyridine N atom of the N,N-diethyl­nicotinamide (DENA) ligand. The Zn atom is displaced by 0.3326 (2) Å from the plane of the four O atoms, with an average Zn—O distance of 2.0416 (12) Å. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 5.31 (8) and 11.00 (9)°, while the pyridine ring is oriented at dihedral angles of 66.26 (6) and 37.88 (7)° with respect to the benzene rings. Weak intra­molecular C—H⋯O and inter­molecular C—H⋯π inter­actions are present. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971944/ /pubmed/21578613 http://dx.doi.org/10.1107/S1600536809047473 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
Tetra­kis[μ-4-(dimethyl­amino)benzoato-κ(2) O:O′]bis­[(N,N-diethyl­nicotinamide-κN (1))zinc(II)]
title Tetra­kis[μ-4-(dimethyl­amino)benzoato-κ(2) O:O′]bis­[(N,N-diethyl­nicotinamide-κN (1))zinc(II)]
title_full Tetra­kis[μ-4-(dimethyl­amino)benzoato-κ(2) O:O′]bis­[(N,N-diethyl­nicotinamide-κN (1))zinc(II)]
title_fullStr Tetra­kis[μ-4-(dimethyl­amino)benzoato-κ(2) O:O′]bis­[(N,N-diethyl­nicotinamide-κN (1))zinc(II)]
title_full_unstemmed Tetra­kis[μ-4-(dimethyl­amino)benzoato-κ(2) O:O′]bis­[(N,N-diethyl­nicotinamide-κN (1))zinc(II)]
title_short Tetra­kis[μ-4-(dimethyl­amino)benzoato-κ(2) O:O′]bis­[(N,N-diethyl­nicotinamide-κN (1))zinc(II)]
title_sort tetra­kis[μ-4-(dimethyl­amino)benzoato-κ(2) o:o′]bis­[(n,n-diethyl­nicotinamide-κn (1))zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971944/
https://www.ncbi.nlm.nih.gov/pubmed/21578613
http://dx.doi.org/10.1107/S1600536809047473
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