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Tetrakis[μ-4-(dimethylamino)benzoato-κ(2) O:O′]bis[(N,N-diethylnicotinamide-κN (1))zinc(II)]
The title molecule, [Zn(2)(C(9)H(10)NO(2))(4)(C(10)H(14)N(2)O)(2)], is a centrosymmetric binuclear complex, with Zn atoms [Zn⋯Zn′ = 2.8927 (4) Å] bridged by four carboxylate groups from the dimethylaminobenzoate (DMAB) ligands. The four carboxyl O atoms around the Zn atom form a distorted square...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971944/ https://www.ncbi.nlm.nih.gov/pubmed/21578613 http://dx.doi.org/10.1107/S1600536809047473 |
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author | Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali |
author_facet | Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali |
author_sort | Hökelek, Tuncer |
collection | PubMed |
description | The title molecule, [Zn(2)(C(9)H(10)NO(2))(4)(C(10)H(14)N(2)O)(2)], is a centrosymmetric binuclear complex, with Zn atoms [Zn⋯Zn′ = 2.8927 (4) Å] bridged by four carboxylate groups from the dimethylaminobenzoate (DMAB) ligands. The four carboxyl O atoms around the Zn atom form a distorted square-planar arrangement; the distorted square-pyramidal coordination geometry is completed by the pyridine N atom of the N,N-diethylnicotinamide (DENA) ligand. The Zn atom is displaced by 0.3326 (2) Å from the plane of the four O atoms, with an average Zn—O distance of 2.0416 (12) Å. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 5.31 (8) and 11.00 (9)°, while the pyridine ring is oriented at dihedral angles of 66.26 (6) and 37.88 (7)° with respect to the benzene rings. Weak intramolecular C—H⋯O and intermolecular C—H⋯π interactions are present. |
format | Text |
id | pubmed-2971944 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29719442010-12-30 Tetrakis[μ-4-(dimethylamino)benzoato-κ(2) O:O′]bis[(N,N-diethylnicotinamide-κN (1))zinc(II)] Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title molecule, [Zn(2)(C(9)H(10)NO(2))(4)(C(10)H(14)N(2)O)(2)], is a centrosymmetric binuclear complex, with Zn atoms [Zn⋯Zn′ = 2.8927 (4) Å] bridged by four carboxylate groups from the dimethylaminobenzoate (DMAB) ligands. The four carboxyl O atoms around the Zn atom form a distorted square-planar arrangement; the distorted square-pyramidal coordination geometry is completed by the pyridine N atom of the N,N-diethylnicotinamide (DENA) ligand. The Zn atom is displaced by 0.3326 (2) Å from the plane of the four O atoms, with an average Zn—O distance of 2.0416 (12) Å. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 5.31 (8) and 11.00 (9)°, while the pyridine ring is oriented at dihedral angles of 66.26 (6) and 37.88 (7)° with respect to the benzene rings. Weak intramolecular C—H⋯O and intermolecular C—H⋯π interactions are present. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971944/ /pubmed/21578613 http://dx.doi.org/10.1107/S1600536809047473 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Tetrakis[μ-4-(dimethylamino)benzoato-κ(2) O:O′]bis[(N,N-diethylnicotinamide-κN (1))zinc(II)] |
title | Tetrakis[μ-4-(dimethylamino)benzoato-κ(2)
O:O′]bis[(N,N-diethylnicotinamide-κN
(1))zinc(II)] |
title_full | Tetrakis[μ-4-(dimethylamino)benzoato-κ(2)
O:O′]bis[(N,N-diethylnicotinamide-κN
(1))zinc(II)] |
title_fullStr | Tetrakis[μ-4-(dimethylamino)benzoato-κ(2)
O:O′]bis[(N,N-diethylnicotinamide-κN
(1))zinc(II)] |
title_full_unstemmed | Tetrakis[μ-4-(dimethylamino)benzoato-κ(2)
O:O′]bis[(N,N-diethylnicotinamide-κN
(1))zinc(II)] |
title_short | Tetrakis[μ-4-(dimethylamino)benzoato-κ(2)
O:O′]bis[(N,N-diethylnicotinamide-κN
(1))zinc(II)] |
title_sort | tetrakis[μ-4-(dimethylamino)benzoato-κ(2)
o:o′]bis[(n,n-diethylnicotinamide-κn
(1))zinc(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971944/ https://www.ncbi.nlm.nih.gov/pubmed/21578613 http://dx.doi.org/10.1107/S1600536809047473 |
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