trans-Dibromidobis[diphen­yl(p-tol­yl)phosphine]palladium(II)

In the title compound, [PdBr(2)(C(19)H(17)P)(2)], the Pd(II) ion resides on a centre of symmetry and is coordinated by two Br anions [Pd—Br = 2.4266 (2) Å] and two P-donor ligands [Pd—P = 2.3462 (5) Å] in a slightly distorted square-planar geometry [P—Pd—Br = 93.528 (12)°]. Weak inter­molecular C—H⋯...

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Detalles Bibliográficos
Autores principales: Kirsten, Leo, Steyl, Gideon, Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971950/
https://www.ncbi.nlm.nih.gov/pubmed/21578600
http://dx.doi.org/10.1107/S1600536809045401
Descripción
Sumario:In the title compound, [PdBr(2)(C(19)H(17)P)(2)], the Pd(II) ion resides on a centre of symmetry and is coordinated by two Br anions [Pd—Br = 2.4266 (2) Å] and two P-donor ligands [Pd—P = 2.3462 (5) Å] in a slightly distorted square-planar geometry [P—Pd—Br = 93.528 (12)°]. Weak inter­molecular C—H⋯Br hydrogen bonds link mol­ecules into chains extended in [1[Image: see text]0].

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