trans-Dibromidobis[diphen­yl(p-tol­yl)phosphine]palladium(II)

In the title compound, [PdBr(2)(C(19)H(17)P)(2)], the Pd(II) ion resides on a centre of symmetry and is coordinated by two Br anions [Pd—Br = 2.4266 (2) Å] and two P-donor ligands [Pd—P = 2.3462 (5) Å] in a slightly distorted square-planar geometry [P—Pd—Br = 93.528 (12)°]. Weak inter­molecular C—H⋯...

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Detalles Bibliográficos
Autores principales: Kirsten, Leo, Steyl, Gideon, Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971950/
https://www.ncbi.nlm.nih.gov/pubmed/21578600
http://dx.doi.org/10.1107/S1600536809045401
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author Kirsten, Leo
Steyl, Gideon
Roodt, Andreas
author_facet Kirsten, Leo
Steyl, Gideon
Roodt, Andreas
author_sort Kirsten, Leo
collection PubMed
description In the title compound, [PdBr(2)(C(19)H(17)P)(2)], the Pd(II) ion resides on a centre of symmetry and is coordinated by two Br anions [Pd—Br = 2.4266 (2) Å] and two P-donor ligands [Pd—P = 2.3462 (5) Å] in a slightly distorted square-planar geometry [P—Pd—Br = 93.528 (12)°]. Weak inter­molecular C—H⋯Br hydrogen bonds link mol­ecules into chains extended in [1[Image: see text]0].
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spelling pubmed-29719502010-12-30 trans-Dibromidobis[diphen­yl(p-tol­yl)phosphine]palladium(II) Kirsten, Leo Steyl, Gideon Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdBr(2)(C(19)H(17)P)(2)], the Pd(II) ion resides on a centre of symmetry and is coordinated by two Br anions [Pd—Br = 2.4266 (2) Å] and two P-donor ligands [Pd—P = 2.3462 (5) Å] in a slightly distorted square-planar geometry [P—Pd—Br = 93.528 (12)°]. Weak inter­molecular C—H⋯Br hydrogen bonds link mol­ecules into chains extended in [1[Image: see text]0]. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971950/ /pubmed/21578600 http://dx.doi.org/10.1107/S1600536809045401 Text en © Kirsten et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kirsten, Leo
Steyl, Gideon
Roodt, Andreas
trans-Dibromidobis[diphen­yl(p-tol­yl)phosphine]palladium(II)
title trans-Dibromidobis[diphen­yl(p-tol­yl)phosphine]palladium(II)
title_full trans-Dibromidobis[diphen­yl(p-tol­yl)phosphine]palladium(II)
title_fullStr trans-Dibromidobis[diphen­yl(p-tol­yl)phosphine]palladium(II)
title_full_unstemmed trans-Dibromidobis[diphen­yl(p-tol­yl)phosphine]palladium(II)
title_short trans-Dibromidobis[diphen­yl(p-tol­yl)phosphine]palladium(II)
title_sort trans-dibromidobis[diphen­yl(p-tol­yl)phosphine]palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971950/
https://www.ncbi.nlm.nih.gov/pubmed/21578600
http://dx.doi.org/10.1107/S1600536809045401
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AT steylgideon transdibromidobisdiphenylptolylphosphinepalladiumii
AT roodtandreas transdibromidobisdiphenylptolylphosphinepalladiumii

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