Tris{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolate-κ(2) O,O′}tris­(thio­cyanato-κN)lanthanum(III)

In the title compound, [La(NCS)(3)(C(15)H(15)NO(2))(3)], the metal centre is nine-coordinated by six O atoms from three zwitterionic Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)iminio­meth­yl]phenolate (L) ligands and three terminal N atoms of the thio­cyanate ions in a monocapped square-anti­prisma...

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Detalles Bibliográficos
Autores principales: Liu, Jian-Feng, Shen, Jin-Bei, Liu, Jia-Lu, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971951/
https://www.ncbi.nlm.nih.gov/pubmed/21578662
http://dx.doi.org/10.1107/S1600536809049113
Descripción
Sumario:In the title compound, [La(NCS)(3)(C(15)H(15)NO(2))(3)], the metal centre is nine-coordinated by six O atoms from three zwitterionic Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)iminio­meth­yl]phenolate (L) ligands and three terminal N atoms of the thio­cyanate ions in a monocapped square-anti­prismatic environment. The L ligands chelate the La(III) ion with strong La—O(deprotonated phenolic) bonds [2.435 (3)–2.464 (3) Å] and significantly longer La—O(meth­oxy) bonds [2.801 (3)–2.831 (3) Å]. The La—N bond lengths range from 2.541 (4) to 2.605 (4) Å.

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