Cargando…
Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2) O,O′}tris(thiocyanato-κN)lanthanum(III)
In the title compound, [La(NCS)(3)(C(15)H(15)NO(2))(3)], the metal centre is nine-coordinated by six O atoms from three zwitterionic Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate (L) ligands and three terminal N atoms of the thiocyanate ions in a monocapped square-antiprisma...
| Autores principales: | , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971951/ https://www.ncbi.nlm.nih.gov/pubmed/21578662 http://dx.doi.org/10.1107/S1600536809049113 |
| _version_ | 1782190708486045696 |
|---|---|
| author | Liu, Jian-Feng Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang |
| author_facet | Liu, Jian-Feng Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang |
| author_sort | Liu, Jian-Feng |
| collection | PubMed |
| description | In the title compound, [La(NCS)(3)(C(15)H(15)NO(2))(3)], the metal centre is nine-coordinated by six O atoms from three zwitterionic Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate (L) ligands and three terminal N atoms of the thiocyanate ions in a monocapped square-antiprismatic environment. The L ligands chelate the La(III) ion with strong La—O(deprotonated phenolic) bonds [2.435 (3)–2.464 (3) Å] and significantly longer La—O(methoxy) bonds [2.801 (3)–2.831 (3) Å]. The La—N bond lengths range from 2.541 (4) to 2.605 (4) Å. |
| format | Text |
| id | pubmed-2971951 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29719512010-12-30 Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2) O,O′}tris(thiocyanato-κN)lanthanum(III) Liu, Jian-Feng Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [La(NCS)(3)(C(15)H(15)NO(2))(3)], the metal centre is nine-coordinated by six O atoms from three zwitterionic Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate (L) ligands and three terminal N atoms of the thiocyanate ions in a monocapped square-antiprismatic environment. The L ligands chelate the La(III) ion with strong La—O(deprotonated phenolic) bonds [2.435 (3)–2.464 (3) Å] and significantly longer La—O(methoxy) bonds [2.801 (3)–2.831 (3) Å]. The La—N bond lengths range from 2.541 (4) to 2.605 (4) Å. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971951/ /pubmed/21578662 http://dx.doi.org/10.1107/S1600536809049113 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Jian-Feng Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2) O,O′}tris(thiocyanato-κN)lanthanum(III) |
| title | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2)
O,O′}tris(thiocyanato-κN)lanthanum(III) |
| title_full | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2)
O,O′}tris(thiocyanato-κN)lanthanum(III) |
| title_fullStr | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2)
O,O′}tris(thiocyanato-κN)lanthanum(III) |
| title_full_unstemmed | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2)
O,O′}tris(thiocyanato-κN)lanthanum(III) |
| title_short | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2)
O,O′}tris(thiocyanato-κN)lanthanum(III) |
| title_sort | tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2)
o,o′}tris(thiocyanato-κn)lanthanum(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971951/ https://www.ncbi.nlm.nih.gov/pubmed/21578662 http://dx.doi.org/10.1107/S1600536809049113 |
| work_keys_str_mv | AT liujianfeng tris2methoxy64methylphenyliminiomethylphenolatek2ootristhiocyanatoknlanthanumiii AT shenjinbei tris2methoxy64methylphenyliminiomethylphenolatek2ootristhiocyanatoknlanthanumiii AT liujialu tris2methoxy64methylphenyliminiomethylphenolatek2ootristhiocyanatoknlanthanumiii AT zhaoguoliang tris2methoxy64methylphenyliminiomethylphenolatek2ootristhiocyanatoknlanthanumiii |