4-(2-Hydroxy­ethyl)anilinium 3-carb­oxy-4-hydroxy­benzene­sulfonate monohydrate

In the structure of the title compound, C(8)H(12)NO(+)·C(7)H(5)O(6)S(−)·H(2)O, isolated from the reaction of 2-(4-amino­phen­yl)ethanol with 5-sulfosalicylic acid, the cations form head-to-tail hydrogen-bonded chains through C (1) (1)(9) anilinium N(+)—H⋯O(hydrox­yl) inter­actions while the anions a...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971952/
https://www.ncbi.nlm.nih.gov/pubmed/21578917
http://dx.doi.org/10.1107/S1600536809049745
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author Smith, Graham
Wermuth, Urs D.
author_facet Smith, Graham
Wermuth, Urs D.
author_sort Smith, Graham
collection PubMed
description In the structure of the title compound, C(8)H(12)NO(+)·C(7)H(5)O(6)S(−)·H(2)O, isolated from the reaction of 2-(4-amino­phen­yl)ethanol with 5-sulfosalicylic acid, the cations form head-to-tail hydrogen-bonded chains through C (1) (1)(9) anilinium N(+)—H⋯O(hydrox­yl) inter­actions while the anions also form parallel but C (1) (1)(8)-linked chains through carboxylic acid O—H⋯O(sulfonate) inter­actions. These chains inter-associate through a number of N(+)—H⋯O and O—H⋯O bridging inter­actions, giving a two-dimensional array in the ab plane.
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spelling pubmed-29719522010-12-30 4-(2-Hydroxy­ethyl)anilinium 3-carb­oxy-4-hydroxy­benzene­sulfonate monohydrate Smith, Graham Wermuth, Urs D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title compound, C(8)H(12)NO(+)·C(7)H(5)O(6)S(−)·H(2)O, isolated from the reaction of 2-(4-amino­phen­yl)ethanol with 5-sulfosalicylic acid, the cations form head-to-tail hydrogen-bonded chains through C (1) (1)(9) anilinium N(+)—H⋯O(hydrox­yl) inter­actions while the anions also form parallel but C (1) (1)(8)-linked chains through carboxylic acid O—H⋯O(sulfonate) inter­actions. These chains inter-associate through a number of N(+)—H⋯O and O—H⋯O bridging inter­actions, giving a two-dimensional array in the ab plane. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971952/ /pubmed/21578917 http://dx.doi.org/10.1107/S1600536809049745 Text en © Smith and Wermuth 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Smith, Graham
Wermuth, Urs D.
4-(2-Hydroxy­ethyl)anilinium 3-carb­oxy-4-hydroxy­benzene­sulfonate monohydrate
title 4-(2-Hydroxy­ethyl)anilinium 3-carb­oxy-4-hydroxy­benzene­sulfonate monohydrate
title_full 4-(2-Hydroxy­ethyl)anilinium 3-carb­oxy-4-hydroxy­benzene­sulfonate monohydrate
title_fullStr 4-(2-Hydroxy­ethyl)anilinium 3-carb­oxy-4-hydroxy­benzene­sulfonate monohydrate
title_full_unstemmed 4-(2-Hydroxy­ethyl)anilinium 3-carb­oxy-4-hydroxy­benzene­sulfonate monohydrate
title_short 4-(2-Hydroxy­ethyl)anilinium 3-carb­oxy-4-hydroxy­benzene­sulfonate monohydrate
title_sort 4-(2-hydroxy­ethyl)anilinium 3-carb­oxy-4-hydroxy­benzene­sulfonate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971952/
https://www.ncbi.nlm.nih.gov/pubmed/21578917
http://dx.doi.org/10.1107/S1600536809049745
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AT wermuthursd 42hydroxyethylanilinium3carboxy4hydroxybenzenesulfonatemonohydrate

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