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Dichloridobis(4-chloro­benz­yl)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)tin(IV)

The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(12)H(12)N(2))], is coordinated by the bidentate N-heterocycle mol­ecule, two chloro­benzyl anions and two Cl(−) anions in a distorted trans-C(2)SnCl(2)N(2) octa­hedral geometry [C—Sn—C = 178.4 (1)°]. In the mol­ecular structure, the tw...

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Detalles Bibliográficos
Autores principales: Keng, Thy Chun, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971954/
https://www.ncbi.nlm.nih.gov/pubmed/21578683
http://dx.doi.org/10.1107/S1600536809049381
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author Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_facet Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_sort Keng, Thy Chun
collection PubMed
description The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(12)H(12)N(2))], is coordinated by the bidentate N-heterocycle mol­ecule, two chloro­benzyl anions and two Cl(−) anions in a distorted trans-C(2)SnCl(2)N(2) octa­hedral geometry [C—Sn—C = 178.4 (1)°]. In the mol­ecular structure, the two benzene rings are oriented at a dihedral angle of 39.62 (17)°.
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spelling pubmed-29719542010-12-30 Dichloridobis(4-chloro­benz­yl)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)tin(IV) Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(12)H(12)N(2))], is coordinated by the bidentate N-heterocycle mol­ecule, two chloro­benzyl anions and two Cl(−) anions in a distorted trans-C(2)SnCl(2)N(2) octa­hedral geometry [C—Sn—C = 178.4 (1)°]. In the mol­ecular structure, the two benzene rings are oriented at a dihedral angle of 39.62 (17)°. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971954/ /pubmed/21578683 http://dx.doi.org/10.1107/S1600536809049381 Text en © Keng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
Dichloridobis(4-chloro­benz­yl)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)tin(IV)
title Dichloridobis(4-chloro­benz­yl)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)tin(IV)
title_full Dichloridobis(4-chloro­benz­yl)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)tin(IV)
title_fullStr Dichloridobis(4-chloro­benz­yl)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)tin(IV)
title_full_unstemmed Dichloridobis(4-chloro­benz­yl)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)tin(IV)
title_short Dichloridobis(4-chloro­benz­yl)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)tin(IV)
title_sort dichloridobis(4-chloro­benz­yl)(4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971954/
https://www.ncbi.nlm.nih.gov/pubmed/21578683
http://dx.doi.org/10.1107/S1600536809049381
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