Bis[2-(morpholinometh­yl)phen­yl]phenyl­phosphane

The title compound, C(28)H(33)N(2)O(2)P, contains a penta­coordinated P atom as a result of the weak N→P intra­molecular inter­actions, with three C atoms, two N atoms and the lone pair arranged in a dicapped pseudo-tetra­hedral geometry. The morpholine rings exhibit an almost ideal chair conformati...

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Detalles Bibliográficos
Autores principales: Covaci, Ancuta, Varga, Richard A., Silvestru, Cristian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971958/
https://www.ncbi.nlm.nih.gov/pubmed/21578876
http://dx.doi.org/10.1107/S1600536809048946
Descripción
Sumario:The title compound, C(28)H(33)N(2)O(2)P, contains a penta­coordinated P atom as a result of the weak N→P intra­molecular inter­actions, with three C atoms, two N atoms and the lone pair arranged in a dicapped pseudo-tetra­hedral geometry. The morpholine rings exhibit an almost ideal chair conformation. In the crystal, two weak C—H⋯O hydrogen-bond inter­actions link the mol­ecules in layers stacked along the a axis; there are no further inter­actions between the layers.

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