Bis[2-(morpholinometh­yl)phen­yl]phenyl­phosphane

The title compound, C(28)H(33)N(2)O(2)P, contains a penta­coordinated P atom as a result of the weak N→P intra­molecular inter­actions, with three C atoms, two N atoms and the lone pair arranged in a dicapped pseudo-tetra­hedral geometry. The morpholine rings exhibit an almost ideal chair conformati...

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Detalles Bibliográficos
Autores principales: Covaci, Ancuta, Varga, Richard A., Silvestru, Cristian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971958/
https://www.ncbi.nlm.nih.gov/pubmed/21578876
http://dx.doi.org/10.1107/S1600536809048946
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author Covaci, Ancuta
Varga, Richard A.
Silvestru, Cristian
author_facet Covaci, Ancuta
Varga, Richard A.
Silvestru, Cristian
author_sort Covaci, Ancuta
collection PubMed
description The title compound, C(28)H(33)N(2)O(2)P, contains a penta­coordinated P atom as a result of the weak N→P intra­molecular inter­actions, with three C atoms, two N atoms and the lone pair arranged in a dicapped pseudo-tetra­hedral geometry. The morpholine rings exhibit an almost ideal chair conformation. In the crystal, two weak C—H⋯O hydrogen-bond inter­actions link the mol­ecules in layers stacked along the a axis; there are no further inter­actions between the layers.
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spelling pubmed-29719582010-12-30 Bis[2-(morpholinometh­yl)phen­yl]phenyl­phosphane Covaci, Ancuta Varga, Richard A. Silvestru, Cristian Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(28)H(33)N(2)O(2)P, contains a penta­coordinated P atom as a result of the weak N→P intra­molecular inter­actions, with three C atoms, two N atoms and the lone pair arranged in a dicapped pseudo-tetra­hedral geometry. The morpholine rings exhibit an almost ideal chair conformation. In the crystal, two weak C—H⋯O hydrogen-bond inter­actions link the mol­ecules in layers stacked along the a axis; there are no further inter­actions between the layers. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971958/ /pubmed/21578876 http://dx.doi.org/10.1107/S1600536809048946 Text en © Covaci et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Covaci, Ancuta
Varga, Richard A.
Silvestru, Cristian
Bis[2-(morpholinometh­yl)phen­yl]phenyl­phosphane
title Bis[2-(morpholinometh­yl)phen­yl]phenyl­phosphane
title_full Bis[2-(morpholinometh­yl)phen­yl]phenyl­phosphane
title_fullStr Bis[2-(morpholinometh­yl)phen­yl]phenyl­phosphane
title_full_unstemmed Bis[2-(morpholinometh­yl)phen­yl]phenyl­phosphane
title_short Bis[2-(morpholinometh­yl)phen­yl]phenyl­phosphane
title_sort bis[2-(morpholinometh­yl)phen­yl]phenyl­phosphane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971958/
https://www.ncbi.nlm.nih.gov/pubmed/21578876
http://dx.doi.org/10.1107/S1600536809048946
work_keys_str_mv AT covaciancuta bis2morpholinomethylphenylphenylphosphane
AT vargaricharda bis2morpholinomethylphenylphenylphosphane
AT silvestrucristian bis2morpholinomethylphenylphenylphosphane

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