Methyl 4,5-diacet­oxy-1-oxo-2-phenyl­perhydro-4,6-epoxy­cyclo­penta­[c]pyridine-7-carboxyl­ate ethanol solvate

The title compound, the product of an acid-catalysed Wagner–Meerwein skeletal rearrangement, crystallizes as an ethanol monosolvate, C(20)H(21)NO(8)·C(2)H(6)O. The title mol­ecule comprises a fused tricyclic system containing two five-membered rings (cyclo­pentane and tetra­hydro­furan) in the usual...

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Autores principales: Gurbanov, Atash V., Nikitina, Eugeniya V., Airiyan, Inga K., Zaytsev, Vladimir P., Khrustalev, Victor N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971959/
https://www.ncbi.nlm.nih.gov/pubmed/21578721
http://dx.doi.org/10.1107/S1600536809045528
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author Gurbanov, Atash V.
Nikitina, Eugeniya V.
Airiyan, Inga K.
Zaytsev, Vladimir P.
Khrustalev, Victor N.
author_facet Gurbanov, Atash V.
Nikitina, Eugeniya V.
Airiyan, Inga K.
Zaytsev, Vladimir P.
Khrustalev, Victor N.
author_sort Gurbanov, Atash V.
collection PubMed
description The title compound, the product of an acid-catalysed Wagner–Meerwein skeletal rearrangement, crystallizes as an ethanol monosolvate, C(20)H(21)NO(8)·C(2)H(6)O. The title mol­ecule comprises a fused tricyclic system containing two five-membered rings (cyclo­pentane and tetra­hydro­furan) in the usual envelope conformations and one six-membered ring (piperidinone) adopting a flattened twist–boat conformation.
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spelling pubmed-29719592010-12-30 Methyl 4,5-diacet­oxy-1-oxo-2-phenyl­perhydro-4,6-epoxy­cyclo­penta­[c]pyridine-7-carboxyl­ate ethanol solvate Gurbanov, Atash V. Nikitina, Eugeniya V. Airiyan, Inga K. Zaytsev, Vladimir P. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, the product of an acid-catalysed Wagner–Meerwein skeletal rearrangement, crystallizes as an ethanol monosolvate, C(20)H(21)NO(8)·C(2)H(6)O. The title mol­ecule comprises a fused tricyclic system containing two five-membered rings (cyclo­pentane and tetra­hydro­furan) in the usual envelope conformations and one six-membered ring (piperidinone) adopting a flattened twist–boat conformation. International Union of Crystallography 2009-11-04 /pmc/articles/PMC2971959/ /pubmed/21578721 http://dx.doi.org/10.1107/S1600536809045528 Text en © Gurbanov et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gurbanov, Atash V.
Nikitina, Eugeniya V.
Airiyan, Inga K.
Zaytsev, Vladimir P.
Khrustalev, Victor N.
Methyl 4,5-diacet­oxy-1-oxo-2-phenyl­perhydro-4,6-epoxy­cyclo­penta­[c]pyridine-7-carboxyl­ate ethanol solvate
title Methyl 4,5-diacet­oxy-1-oxo-2-phenyl­perhydro-4,6-epoxy­cyclo­penta­[c]pyridine-7-carboxyl­ate ethanol solvate
title_full Methyl 4,5-diacet­oxy-1-oxo-2-phenyl­perhydro-4,6-epoxy­cyclo­penta­[c]pyridine-7-carboxyl­ate ethanol solvate
title_fullStr Methyl 4,5-diacet­oxy-1-oxo-2-phenyl­perhydro-4,6-epoxy­cyclo­penta­[c]pyridine-7-carboxyl­ate ethanol solvate
title_full_unstemmed Methyl 4,5-diacet­oxy-1-oxo-2-phenyl­perhydro-4,6-epoxy­cyclo­penta­[c]pyridine-7-carboxyl­ate ethanol solvate
title_short Methyl 4,5-diacet­oxy-1-oxo-2-phenyl­perhydro-4,6-epoxy­cyclo­penta­[c]pyridine-7-carboxyl­ate ethanol solvate
title_sort methyl 4,5-diacet­oxy-1-oxo-2-phenyl­perhydro-4,6-epoxy­cyclo­penta­[c]pyridine-7-carboxyl­ate ethanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971959/
https://www.ncbi.nlm.nih.gov/pubmed/21578721
http://dx.doi.org/10.1107/S1600536809045528
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