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4,4′-(Ethene-1,2-diyl)dipyridinium bis[4-(2-carboxybenzoyl)benzoate]
In the crystal structure of the title compound, C(12)H(12)N(2) (2+)·2C(15)H(9)O(5) (−), the cation has site symmetry [Image: see text] with the mid-point of C=C bond located on an inversion center. The two benzene rings of the anion are oriented at a dihedral angle 85.87 (6)°. In the crystal, inter...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971962/ https://www.ncbi.nlm.nih.gov/pubmed/21578927 http://dx.doi.org/10.1107/S1600536809048417 |
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author | Li, Cai Li, Dong-Sheng Zhao, Jun Zheng, Xue-Gang Ke, Xi-Jun |
author_facet | Li, Cai Li, Dong-Sheng Zhao, Jun Zheng, Xue-Gang Ke, Xi-Jun |
author_sort | Li, Cai |
collection | PubMed |
description | In the crystal structure of the title compound, C(12)H(12)N(2) (2+)·2C(15)H(9)O(5) (−), the cation has site symmetry [Image: see text] with the mid-point of C=C bond located on an inversion center. The two benzene rings of the anion are oriented at a dihedral angle 85.87 (6)°. In the crystal, intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the cations and anions into supramolecular double chains, which are further connected into a three-dimensional network through intermolecular C—H⋯O and π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.4413 (12)Å] and between parallel benzene rings [centroid–centroid distance = 3.6116 (14)Å]. |
format | Text |
id | pubmed-2971962 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29719622010-12-30 4,4′-(Ethene-1,2-diyl)dipyridinium bis[4-(2-carboxybenzoyl)benzoate] Li, Cai Li, Dong-Sheng Zhao, Jun Zheng, Xue-Gang Ke, Xi-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(12)H(12)N(2) (2+)·2C(15)H(9)O(5) (−), the cation has site symmetry [Image: see text] with the mid-point of C=C bond located on an inversion center. The two benzene rings of the anion are oriented at a dihedral angle 85.87 (6)°. In the crystal, intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the cations and anions into supramolecular double chains, which are further connected into a three-dimensional network through intermolecular C—H⋯O and π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.4413 (12)Å] and between parallel benzene rings [centroid–centroid distance = 3.6116 (14)Å]. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971962/ /pubmed/21578927 http://dx.doi.org/10.1107/S1600536809048417 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Cai Li, Dong-Sheng Zhao, Jun Zheng, Xue-Gang Ke, Xi-Jun 4,4′-(Ethene-1,2-diyl)dipyridinium bis[4-(2-carboxybenzoyl)benzoate] |
title | 4,4′-(Ethene-1,2-diyl)dipyridinium bis[4-(2-carboxybenzoyl)benzoate] |
title_full | 4,4′-(Ethene-1,2-diyl)dipyridinium bis[4-(2-carboxybenzoyl)benzoate] |
title_fullStr | 4,4′-(Ethene-1,2-diyl)dipyridinium bis[4-(2-carboxybenzoyl)benzoate] |
title_full_unstemmed | 4,4′-(Ethene-1,2-diyl)dipyridinium bis[4-(2-carboxybenzoyl)benzoate] |
title_short | 4,4′-(Ethene-1,2-diyl)dipyridinium bis[4-(2-carboxybenzoyl)benzoate] |
title_sort | 4,4′-(ethene-1,2-diyl)dipyridinium bis[4-(2-carboxybenzoyl)benzoate] |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971962/ https://www.ncbi.nlm.nih.gov/pubmed/21578927 http://dx.doi.org/10.1107/S1600536809048417 |
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