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4,4′-(Ethene-1,2-diyl)dipyridinium bis­[4-(2-carboxy­benzo­yl)benzoate]

In the crystal structure of the title compound, C(12)H(12)N(2) (2+)·2C(15)H(9)O(5) (−), the cation has site symmetry [Image: see text] with the mid-point of C=C bond located on an inversion center. The two benzene rings of the anion are oriented at a dihedral angle 85.87 (6)°. In the crystal, inter­...

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Detalles Bibliográficos
Autores principales: Li, Cai, Li, Dong-Sheng, Zhao, Jun, Zheng, Xue-Gang, Ke, Xi-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971962/
https://www.ncbi.nlm.nih.gov/pubmed/21578927
http://dx.doi.org/10.1107/S1600536809048417
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author Li, Cai
Li, Dong-Sheng
Zhao, Jun
Zheng, Xue-Gang
Ke, Xi-Jun
author_facet Li, Cai
Li, Dong-Sheng
Zhao, Jun
Zheng, Xue-Gang
Ke, Xi-Jun
author_sort Li, Cai
collection PubMed
description In the crystal structure of the title compound, C(12)H(12)N(2) (2+)·2C(15)H(9)O(5) (−), the cation has site symmetry [Image: see text] with the mid-point of C=C bond located on an inversion center. The two benzene rings of the anion are oriented at a dihedral angle 85.87 (6)°. In the crystal, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the cations and anions into supra­molecular double chains, which are further connected into a three-dimensional network through inter­molecular C—H⋯O and π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.4413 (12)Å] and between parallel benzene rings [centroid–centroid distance = 3.6116 (14)Å].
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spelling pubmed-29719622010-12-30 4,4′-(Ethene-1,2-diyl)dipyridinium bis­[4-(2-carboxy­benzo­yl)benzoate] Li, Cai Li, Dong-Sheng Zhao, Jun Zheng, Xue-Gang Ke, Xi-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(12)H(12)N(2) (2+)·2C(15)H(9)O(5) (−), the cation has site symmetry [Image: see text] with the mid-point of C=C bond located on an inversion center. The two benzene rings of the anion are oriented at a dihedral angle 85.87 (6)°. In the crystal, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the cations and anions into supra­molecular double chains, which are further connected into a three-dimensional network through inter­molecular C—H⋯O and π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.4413 (12)Å] and between parallel benzene rings [centroid–centroid distance = 3.6116 (14)Å]. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971962/ /pubmed/21578927 http://dx.doi.org/10.1107/S1600536809048417 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Cai
Li, Dong-Sheng
Zhao, Jun
Zheng, Xue-Gang
Ke, Xi-Jun
4,4′-(Ethene-1,2-diyl)dipyridinium bis­[4-(2-carboxy­benzo­yl)benzoate]
title 4,4′-(Ethene-1,2-diyl)dipyridinium bis­[4-(2-carboxy­benzo­yl)benzoate]
title_full 4,4′-(Ethene-1,2-diyl)dipyridinium bis­[4-(2-carboxy­benzo­yl)benzoate]
title_fullStr 4,4′-(Ethene-1,2-diyl)dipyridinium bis­[4-(2-carboxy­benzo­yl)benzoate]
title_full_unstemmed 4,4′-(Ethene-1,2-diyl)dipyridinium bis­[4-(2-carboxy­benzo­yl)benzoate]
title_short 4,4′-(Ethene-1,2-diyl)dipyridinium bis­[4-(2-carboxy­benzo­yl)benzoate]
title_sort 4,4′-(ethene-1,2-diyl)dipyridinium bis­[4-(2-carboxy­benzo­yl)benzoate]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971962/
https://www.ncbi.nlm.nih.gov/pubmed/21578927
http://dx.doi.org/10.1107/S1600536809048417
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