Chloridocyclo­hexyl[(1,2,5,6-η)-cyclo­octa-1,5-diene]platinum(II)

In the title complex, [Pt(C(6)H(11))Cl(C(8)H(12))], the Pt(II) ion lies in a distorted square-planar environment defined by the Cl and cyclo­hexyl C atoms and the mid-points of the two π-coordinated double bonds of cyclo­octa-1,5-diene. As a result of the different trans influences of the Cl atom an...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971967/
https://www.ncbi.nlm.nih.gov/pubmed/21578708
http://dx.doi.org/10.1107/S1600536809050910
Descripción
Sumario:In the title complex, [Pt(C(6)H(11))Cl(C(8)H(12))], the Pt(II) ion lies in a distorted square-planar environment defined by the Cl and cyclo­hexyl C atoms and the mid-points of the two π-coordinated double bonds of cyclo­octa-1,5-diene. As a result of the different trans influences of the Cl atom and the cyclo­hexyl group, the Pt—C bonds trans to the cyclo­hexyl group are longer than those trans to the Cl atom.

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