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meso-4,5-Diphenylimidazolidin-2-one
The crystal structure determination of the title compound, C(15)H(14)N(2)O, confirms the cis relationship between the phenyl groups at the 4- and 5-positions on the imidazolidine ring. The dihedral angle between the two phenyl rings is 48.14 (6)°. In the crystal structure, intermolecular N—H⋯O hydr...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971968/ https://www.ncbi.nlm.nih.gov/pubmed/21578817 http://dx.doi.org/10.1107/S1600536809046133 |
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author | Galas, Henry Viirre, Russell D. Lough, Alan J. |
author_facet | Galas, Henry Viirre, Russell D. Lough, Alan J. |
author_sort | Galas, Henry |
collection | PubMed |
description | The crystal structure determination of the title compound, C(15)H(14)N(2)O, confirms the cis relationship between the phenyl groups at the 4- and 5-positions on the imidazolidine ring. The dihedral angle between the two phenyl rings is 48.14 (6)°. In the crystal structure, intermolecular N—H⋯O hydrogen bonds link molecules into centrosymmetric dimers. These dimers are, in turn, linked into a two-dimensional network via weak N—H⋯π(arene) interactions and π–π stacking interactions with centroid–centroid distances of 3.6937 (11) Å. |
format | Text |
id | pubmed-2971968 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29719682010-12-30 meso-4,5-Diphenylimidazolidin-2-one Galas, Henry Viirre, Russell D. Lough, Alan J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure determination of the title compound, C(15)H(14)N(2)O, confirms the cis relationship between the phenyl groups at the 4- and 5-positions on the imidazolidine ring. The dihedral angle between the two phenyl rings is 48.14 (6)°. In the crystal structure, intermolecular N—H⋯O hydrogen bonds link molecules into centrosymmetric dimers. These dimers are, in turn, linked into a two-dimensional network via weak N—H⋯π(arene) interactions and π–π stacking interactions with centroid–centroid distances of 3.6937 (11) Å. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2971968/ /pubmed/21578817 http://dx.doi.org/10.1107/S1600536809046133 Text en © Galas et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Galas, Henry Viirre, Russell D. Lough, Alan J. meso-4,5-Diphenylimidazolidin-2-one |
title |
meso-4,5-Diphenylimidazolidin-2-one |
title_full |
meso-4,5-Diphenylimidazolidin-2-one |
title_fullStr |
meso-4,5-Diphenylimidazolidin-2-one |
title_full_unstemmed |
meso-4,5-Diphenylimidazolidin-2-one |
title_short |
meso-4,5-Diphenylimidazolidin-2-one |
title_sort | meso-4,5-diphenylimidazolidin-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971968/ https://www.ncbi.nlm.nih.gov/pubmed/21578817 http://dx.doi.org/10.1107/S1600536809046133 |
work_keys_str_mv | AT galashenry meso45diphenylimidazolidin2one AT viirrerusselld meso45diphenylimidazolidin2one AT loughalanj meso45diphenylimidazolidin2one |