Chlorido(dimethyl sulfoxide-κO)triphenyl­tin(IV)

In the title compound, [Sn(C(6)H(5))(3)Cl(C(2)H(6)OS)], the Sn(IV) atom is coordinated by three phenyl groups, a chloride ion and a dimethyl sulfoxide mol­ecule in a distorted trigonal-bipyramidal geometry. In the crystal, adjacent mol­ecules are linked through inter­molecular C—H⋯Cl hydrogen bonds,...

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Detalles Bibliográficos
Autores principales: Kumar, Sarvendra, Shadab, Shah Mohammad, Idrees, Mohammad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971969/
https://www.ncbi.nlm.nih.gov/pubmed/21578630
http://dx.doi.org/10.1107/S1600536809048090
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author Kumar, Sarvendra
Shadab, Shah Mohammad
Idrees, Mohammad
author_facet Kumar, Sarvendra
Shadab, Shah Mohammad
Idrees, Mohammad
author_sort Kumar, Sarvendra
collection PubMed
description In the title compound, [Sn(C(6)H(5))(3)Cl(C(2)H(6)OS)], the Sn(IV) atom is coordinated by three phenyl groups, a chloride ion and a dimethyl sulfoxide mol­ecule in a distorted trigonal-bipyramidal geometry. In the crystal, adjacent mol­ecules are linked through inter­molecular C—H⋯Cl hydrogen bonds, weak C—H⋯π inter­actions and π–π inter­actions [centroid–centroid distance = 3.934 (3) Å. An intra­molecular C—H⋯π inter­action is also observed.
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spelling pubmed-29719692010-12-30 Chlorido(dimethyl sulfoxide-κO)triphenyl­tin(IV) Kumar, Sarvendra Shadab, Shah Mohammad Idrees, Mohammad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(C(6)H(5))(3)Cl(C(2)H(6)OS)], the Sn(IV) atom is coordinated by three phenyl groups, a chloride ion and a dimethyl sulfoxide mol­ecule in a distorted trigonal-bipyramidal geometry. In the crystal, adjacent mol­ecules are linked through inter­molecular C—H⋯Cl hydrogen bonds, weak C—H⋯π inter­actions and π–π inter­actions [centroid–centroid distance = 3.934 (3) Å. An intra­molecular C—H⋯π inter­action is also observed. International Union of Crystallography 2009-11-18 /pmc/articles/PMC2971969/ /pubmed/21578630 http://dx.doi.org/10.1107/S1600536809048090 Text en © Kumar et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kumar, Sarvendra
Shadab, Shah Mohammad
Idrees, Mohammad
Chlorido(dimethyl sulfoxide-κO)triphenyl­tin(IV)
title Chlorido(dimethyl sulfoxide-κO)triphenyl­tin(IV)
title_full Chlorido(dimethyl sulfoxide-κO)triphenyl­tin(IV)
title_fullStr Chlorido(dimethyl sulfoxide-κO)triphenyl­tin(IV)
title_full_unstemmed Chlorido(dimethyl sulfoxide-κO)triphenyl­tin(IV)
title_short Chlorido(dimethyl sulfoxide-κO)triphenyl­tin(IV)
title_sort chlorido(dimethyl sulfoxide-κo)triphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971969/
https://www.ncbi.nlm.nih.gov/pubmed/21578630
http://dx.doi.org/10.1107/S1600536809048090
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AT idreesmohammad chloridodimethylsulfoxidekotriphenyltiniv

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