cis-Cyclo­heptane-1,2-diol

The title compound, C(7)H(14)O(2), is a vicinal diol derived from cyclo­heptane with cis-orientated hydr­oxy groups. The mol­ecules shows no non-crystallographic symmetry. The O—C—C—O torsion angles of both mol­ecules present in the asymmetric unit [−66.4 (2) and −66.9 (2)°] are similar to those in...

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Detalles Bibliográficos
Autores principales: Betz, Richard, Klüfers, Peter, Mayer, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971971/
https://www.ncbi.nlm.nih.gov/pubmed/21578965
http://dx.doi.org/10.1107/S160053680905051X
Descripción
Sumario:The title compound, C(7)H(14)O(2), is a vicinal diol derived from cyclo­heptane with cis-orientated hydr­oxy groups. The mol­ecules shows no non-crystallographic symmetry. The O—C—C—O torsion angles of both mol­ecules present in the asymmetric unit [−66.4 (2) and −66.9 (2)°] are similar to those in trans-configured cyclo­hexane derivatives (including pyran­oses) as well as rac-trans-cyclo­heptane-1,2-diol, but smaller than those in trans-configured cyclo­pentane derivatives (including furan­oses). In the crystal structure, O—H⋯O hydrogen bonds furnish the formation of sheets parallel to [110].

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