cis-Cyclo­heptane-1,2-diol

The title compound, C(7)H(14)O(2), is a vicinal diol derived from cyclo­heptane with cis-orientated hydr­oxy groups. The mol­ecules shows no non-crystallographic symmetry. The O—C—C—O torsion angles of both mol­ecules present in the asymmetric unit [−66.4 (2) and −66.9 (2)°] are similar to those in...

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Detalles Bibliográficos
Autores principales: Betz, Richard, Klüfers, Peter, Mayer, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971971/
https://www.ncbi.nlm.nih.gov/pubmed/21578965
http://dx.doi.org/10.1107/S160053680905051X
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author Betz, Richard
Klüfers, Peter
Mayer, Peter
author_facet Betz, Richard
Klüfers, Peter
Mayer, Peter
author_sort Betz, Richard
collection PubMed
description The title compound, C(7)H(14)O(2), is a vicinal diol derived from cyclo­heptane with cis-orientated hydr­oxy groups. The mol­ecules shows no non-crystallographic symmetry. The O—C—C—O torsion angles of both mol­ecules present in the asymmetric unit [−66.4 (2) and −66.9 (2)°] are similar to those in trans-configured cyclo­hexane derivatives (including pyran­oses) as well as rac-trans-cyclo­heptane-1,2-diol, but smaller than those in trans-configured cyclo­pentane derivatives (including furan­oses). In the crystal structure, O—H⋯O hydrogen bonds furnish the formation of sheets parallel to [110].
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spelling pubmed-29719712010-12-30 cis-Cyclo­heptane-1,2-diol Betz, Richard Klüfers, Peter Mayer, Peter Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(7)H(14)O(2), is a vicinal diol derived from cyclo­heptane with cis-orientated hydr­oxy groups. The mol­ecules shows no non-crystallographic symmetry. The O—C—C—O torsion angles of both mol­ecules present in the asymmetric unit [−66.4 (2) and −66.9 (2)°] are similar to those in trans-configured cyclo­hexane derivatives (including pyran­oses) as well as rac-trans-cyclo­heptane-1,2-diol, but smaller than those in trans-configured cyclo­pentane derivatives (including furan­oses). In the crystal structure, O—H⋯O hydrogen bonds furnish the formation of sheets parallel to [110]. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2971971/ /pubmed/21578965 http://dx.doi.org/10.1107/S160053680905051X Text en © Betz et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Betz, Richard
Klüfers, Peter
Mayer, Peter
cis-Cyclo­heptane-1,2-diol
title cis-Cyclo­heptane-1,2-diol
title_full cis-Cyclo­heptane-1,2-diol
title_fullStr cis-Cyclo­heptane-1,2-diol
title_full_unstemmed cis-Cyclo­heptane-1,2-diol
title_short cis-Cyclo­heptane-1,2-diol
title_sort cis-cyclo­heptane-1,2-diol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971971/
https://www.ncbi.nlm.nih.gov/pubmed/21578965
http://dx.doi.org/10.1107/S160053680905051X
work_keys_str_mv AT betzrichard ciscycloheptane12diol
AT kluferspeter ciscycloheptane12diol
AT mayerpeter ciscycloheptane12diol

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