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Bis(1,3-diethyl­benzimidazolium) tetra­bromidomercurate(II)

In the title compound, (C(11)H(15)N(2))(2)[HgBr(4)], the tetra­coordinated Hg(II) center of the complex anion adopts a distorted tetra­hedral geometry [Hg—Br = 2.5755 (8)–2.623 (11) Å and Br—Hg—Br = 103.78 (19)–116.4 (3)°]. One of the Br atoms is disordered over two sites [site-occupancy factors = 0...

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Detalles Bibliográficos
Autores principales: Li, Shu-Juan, Chen, Ai-Hui, Zheng, Zhan-Ying, Liu, Shu-Wan, Liu, Qing-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971972/
https://www.ncbi.nlm.nih.gov/pubmed/21578664
http://dx.doi.org/10.1107/S1600536809047461
Descripción
Sumario:In the title compound, (C(11)H(15)N(2))(2)[HgBr(4)], the tetra­coordinated Hg(II) center of the complex anion adopts a distorted tetra­hedral geometry [Hg—Br = 2.5755 (8)–2.623 (11) Å and Br—Hg—Br = 103.78 (19)–116.4 (3)°]. One of the Br atoms is disordered over two sites [site-occupancy factors = 0.51 (6) and 0.49 (6)]. The N—C—N angles in the cations are 110.7 (6) and 111.4 (7)°. In the crystal packing, a supra­molecular chain is formed via both weak inter­molecular C—H⋯Br hydrogen bonds and π–π aromatic ring stacking inter­actions [centroid–centroid separation = 3.803 (1) Å].