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Bis(1,3-diethylbenzimidazolium) tetrabromidomercurate(II)
In the title compound, (C(11)H(15)N(2))(2)[HgBr(4)], the tetracoordinated Hg(II) center of the complex anion adopts a distorted tetrahedral geometry [Hg—Br = 2.5755 (8)–2.623 (11) Å and Br—Hg—Br = 103.78 (19)–116.4 (3)°]. One of the Br atoms is disordered over two sites [site-occupancy factors = 0...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971972/ https://www.ncbi.nlm.nih.gov/pubmed/21578664 http://dx.doi.org/10.1107/S1600536809047461 |
Sumario: | In the title compound, (C(11)H(15)N(2))(2)[HgBr(4)], the tetracoordinated Hg(II) center of the complex anion adopts a distorted tetrahedral geometry [Hg—Br = 2.5755 (8)–2.623 (11) Å and Br—Hg—Br = 103.78 (19)–116.4 (3)°]. One of the Br atoms is disordered over two sites [site-occupancy factors = 0.51 (6) and 0.49 (6)]. The N—C—N angles in the cations are 110.7 (6) and 111.4 (7)°. In the crystal packing, a supramolecular chain is formed via both weak intermolecular C—H⋯Br hydrogen bonds and π–π aromatic ring stacking interactions [centroid–centroid separation = 3.803 (1) Å]. |
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