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Bis(1,3-diethyl­benzimidazolium) tetra­bromidomercurate(II)

In the title compound, (C(11)H(15)N(2))(2)[HgBr(4)], the tetra­coordinated Hg(II) center of the complex anion adopts a distorted tetra­hedral geometry [Hg—Br = 2.5755 (8)–2.623 (11) Å and Br—Hg—Br = 103.78 (19)–116.4 (3)°]. One of the Br atoms is disordered over two sites [site-occupancy factors = 0...

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Autores principales: Li, Shu-Juan, Chen, Ai-Hui, Zheng, Zhan-Ying, Liu, Shu-Wan, Liu, Qing-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971972/
https://www.ncbi.nlm.nih.gov/pubmed/21578664
http://dx.doi.org/10.1107/S1600536809047461
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author Li, Shu-Juan
Chen, Ai-Hui
Zheng, Zhan-Ying
Liu, Shu-Wan
Liu, Qing-Xiang
author_facet Li, Shu-Juan
Chen, Ai-Hui
Zheng, Zhan-Ying
Liu, Shu-Wan
Liu, Qing-Xiang
author_sort Li, Shu-Juan
collection PubMed
description In the title compound, (C(11)H(15)N(2))(2)[HgBr(4)], the tetra­coordinated Hg(II) center of the complex anion adopts a distorted tetra­hedral geometry [Hg—Br = 2.5755 (8)–2.623 (11) Å and Br—Hg—Br = 103.78 (19)–116.4 (3)°]. One of the Br atoms is disordered over two sites [site-occupancy factors = 0.51 (6) and 0.49 (6)]. The N—C—N angles in the cations are 110.7 (6) and 111.4 (7)°. In the crystal packing, a supra­molecular chain is formed via both weak inter­molecular C—H⋯Br hydrogen bonds and π–π aromatic ring stacking inter­actions [centroid–centroid separation = 3.803 (1) Å].
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spelling pubmed-29719722010-12-30 Bis(1,3-diethyl­benzimidazolium) tetra­bromidomercurate(II) Li, Shu-Juan Chen, Ai-Hui Zheng, Zhan-Ying Liu, Shu-Wan Liu, Qing-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(11)H(15)N(2))(2)[HgBr(4)], the tetra­coordinated Hg(II) center of the complex anion adopts a distorted tetra­hedral geometry [Hg—Br = 2.5755 (8)–2.623 (11) Å and Br—Hg—Br = 103.78 (19)–116.4 (3)°]. One of the Br atoms is disordered over two sites [site-occupancy factors = 0.51 (6) and 0.49 (6)]. The N—C—N angles in the cations are 110.7 (6) and 111.4 (7)°. In the crystal packing, a supra­molecular chain is formed via both weak inter­molecular C—H⋯Br hydrogen bonds and π–π aromatic ring stacking inter­actions [centroid–centroid separation = 3.803 (1) Å]. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971972/ /pubmed/21578664 http://dx.doi.org/10.1107/S1600536809047461 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Shu-Juan
Chen, Ai-Hui
Zheng, Zhan-Ying
Liu, Shu-Wan
Liu, Qing-Xiang
Bis(1,3-diethyl­benzimidazolium) tetra­bromidomercurate(II)
title Bis(1,3-diethyl­benzimidazolium) tetra­bromidomercurate(II)
title_full Bis(1,3-diethyl­benzimidazolium) tetra­bromidomercurate(II)
title_fullStr Bis(1,3-diethyl­benzimidazolium) tetra­bromidomercurate(II)
title_full_unstemmed Bis(1,3-diethyl­benzimidazolium) tetra­bromidomercurate(II)
title_short Bis(1,3-diethyl­benzimidazolium) tetra­bromidomercurate(II)
title_sort bis(1,3-diethyl­benzimidazolium) tetra­bromidomercurate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971972/
https://www.ncbi.nlm.nih.gov/pubmed/21578664
http://dx.doi.org/10.1107/S1600536809047461
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