1-(4-tert-Butyl­benz­yl)-2-(4-tert-butyl­phen­yl)-1H-benzimidazole

In the mol­ecule of the title compound, C(28)H(32)N(2), the benzimidazole ring system is almost planar [maximum deviation = 0.0221 (15) Å] and forms dihedral angles of 85.86 (4) and 32.09 (6)° with the benzene rings. In the crystal structure, mol­ecules are linked into chains running parallel to the...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhou, Jian-Cheng, Zhang, Zheng-Yun, Li, Nai-Xu, Zhang, Chuan-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971974/
https://www.ncbi.nlm.nih.gov/pubmed/21578756
http://dx.doi.org/10.1107/S1600536809045668
_version_ 1782190714040352768
author Zhou, Jian-Cheng
Zhang, Zheng-Yun
Li, Nai-Xu
Zhang, Chuan-Ming
author_facet Zhou, Jian-Cheng
Zhang, Zheng-Yun
Li, Nai-Xu
Zhang, Chuan-Ming
author_sort Zhou, Jian-Cheng
collection PubMed
description In the mol­ecule of the title compound, C(28)H(32)N(2), the benzimidazole ring system is almost planar [maximum deviation = 0.0221 (15) Å] and forms dihedral angles of 85.86 (4) and 32.09 (6)° with the benzene rings. In the crystal structure, mol­ecules are linked into chains running parallel to the a axis by inter­molecular C—H⋯N hydrogen bonds. The methyl groups of a tert-butyl group are rotationally disordered over two positions with refined site-occupancy factors of 0.636 (4) and 0.364 (4).
format Text
id pubmed-2971974
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29719742010-12-30 1-(4-tert-Butyl­benz­yl)-2-(4-tert-butyl­phen­yl)-1H-benzimidazole Zhou, Jian-Cheng Zhang, Zheng-Yun Li, Nai-Xu Zhang, Chuan-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(28)H(32)N(2), the benzimidazole ring system is almost planar [maximum deviation = 0.0221 (15) Å] and forms dihedral angles of 85.86 (4) and 32.09 (6)° with the benzene rings. In the crystal structure, mol­ecules are linked into chains running parallel to the a axis by inter­molecular C—H⋯N hydrogen bonds. The methyl groups of a tert-butyl group are rotationally disordered over two positions with refined site-occupancy factors of 0.636 (4) and 0.364 (4). International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971974/ /pubmed/21578756 http://dx.doi.org/10.1107/S1600536809045668 Text en © Zhou et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhou, Jian-Cheng
Zhang, Zheng-Yun
Li, Nai-Xu
Zhang, Chuan-Ming
1-(4-tert-Butyl­benz­yl)-2-(4-tert-butyl­phen­yl)-1H-benzimidazole
title 1-(4-tert-Butyl­benz­yl)-2-(4-tert-butyl­phen­yl)-1H-benzimidazole
title_full 1-(4-tert-Butyl­benz­yl)-2-(4-tert-butyl­phen­yl)-1H-benzimidazole
title_fullStr 1-(4-tert-Butyl­benz­yl)-2-(4-tert-butyl­phen­yl)-1H-benzimidazole
title_full_unstemmed 1-(4-tert-Butyl­benz­yl)-2-(4-tert-butyl­phen­yl)-1H-benzimidazole
title_short 1-(4-tert-Butyl­benz­yl)-2-(4-tert-butyl­phen­yl)-1H-benzimidazole
title_sort 1-(4-tert-butyl­benz­yl)-2-(4-tert-butyl­phen­yl)-1h-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971974/
https://www.ncbi.nlm.nih.gov/pubmed/21578756
http://dx.doi.org/10.1107/S1600536809045668
work_keys_str_mv AT zhoujiancheng 14tertbutylbenzyl24tertbutylphenyl1hbenzimidazole
AT zhangzhengyun 14tertbutylbenzyl24tertbutylphenyl1hbenzimidazole
AT linaixu 14tertbutylbenzyl24tertbutylphenyl1hbenzimidazole
AT zhangchuanming 14tertbutylbenzyl24tertbutylphenyl1hbenzimidazole

Ejemplares similares