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Diaqua­bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))nickel(II) bis­(3-methyl­benzoate) 3-methyl­benzoic acid disolvate

In the title compound, [Ni(C(6)H(6)N(4))(2)(H(2)O)(2)](C(8)H(7)O(2))(2)·2C(8)H(8)O(2), the Ni(II) atom (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole ligands and two water mol­ecules, resulting in a slightly distorted trans-NiO(2)N(4) geometry for the metal i...

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Detalles Bibliográficos
Autor principal: Hui, Zhou
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971984/
https://www.ncbi.nlm.nih.gov/pubmed/21578548
http://dx.doi.org/10.1107/S1600536809044705
Descripción
Sumario:In the title compound, [Ni(C(6)H(6)N(4))(2)(H(2)O)(2)](C(8)H(7)O(2))(2)·2C(8)H(8)O(2), the Ni(II) atom (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole ligands and two water mol­ecules, resulting in a slightly distorted trans-NiO(2)N(4) geometry for the metal ion. In the crystal, the components are linked by N—H⋯O and O—H⋯O hydrogen bonds, generating an infinite two-dimensional network running parallel to (100). The methyl group of the benzoic acid mol­ecule is disordered over two sites in a 0.563 (17):0.437 (17) ratio.