catena-Poly[[triaqua­(pyridine-κN)nickel(II)]-μ-sulfato-κ(2) O:O′]

The title compound, [Ni(SO(4))(C(5)H(5)N)(H(2)O)(3)](n), was synthesized by the hydro­thermal reaction of NiSO(4)·6H(2)O, pyridine and water. The central Ni(II) atom is coordinated in a distorted octa­hedral environment by a pyridine N atom, three aqua O atoms and two O atoms of bridging sulfate ani...

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Detalles Bibliográficos
Autores principales: Shi, Yan-Fang, Li, Fu-Xing, Geng, Bo, Liu, Yan-Cheng, Chen, Zhen-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971987/
https://www.ncbi.nlm.nih.gov/pubmed/21578675
http://dx.doi.org/10.1107/S1600536809049605
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author Shi, Yan-Fang
Li, Fu-Xing
Geng, Bo
Liu, Yan-Cheng
Chen, Zhen-Feng
author_facet Shi, Yan-Fang
Li, Fu-Xing
Geng, Bo
Liu, Yan-Cheng
Chen, Zhen-Feng
author_sort Shi, Yan-Fang
collection PubMed
description The title compound, [Ni(SO(4))(C(5)H(5)N)(H(2)O)(3)](n), was synthesized by the hydro­thermal reaction of NiSO(4)·6H(2)O, pyridine and water. The central Ni(II) atom is coordinated in a distorted octa­hedral environment by a pyridine N atom, three aqua O atoms and two O atoms of bridging sulfate anions, yielding a zigzag chain. A three-dimensional network is generated via complex hydrogen bonds involving the sulfate and aqua ligands and a pyridine C—H group.
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spelling pubmed-29719872010-12-30 catena-Poly[[triaqua­(pyridine-κN)nickel(II)]-μ-sulfato-κ(2) O:O′] Shi, Yan-Fang Li, Fu-Xing Geng, Bo Liu, Yan-Cheng Chen, Zhen-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(SO(4))(C(5)H(5)N)(H(2)O)(3)](n), was synthesized by the hydro­thermal reaction of NiSO(4)·6H(2)O, pyridine and water. The central Ni(II) atom is coordinated in a distorted octa­hedral environment by a pyridine N atom, three aqua O atoms and two O atoms of bridging sulfate anions, yielding a zigzag chain. A three-dimensional network is generated via complex hydrogen bonds involving the sulfate and aqua ligands and a pyridine C—H group. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2971987/ /pubmed/21578675 http://dx.doi.org/10.1107/S1600536809049605 Text en © Shi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Yan-Fang
Li, Fu-Xing
Geng, Bo
Liu, Yan-Cheng
Chen, Zhen-Feng
catena-Poly[[triaqua­(pyridine-κN)nickel(II)]-μ-sulfato-κ(2) O:O′]
title catena-Poly[[triaqua­(pyridine-κN)nickel(II)]-μ-sulfato-κ(2) O:O′]
title_full catena-Poly[[triaqua­(pyridine-κN)nickel(II)]-μ-sulfato-κ(2) O:O′]
title_fullStr catena-Poly[[triaqua­(pyridine-κN)nickel(II)]-μ-sulfato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[triaqua­(pyridine-κN)nickel(II)]-μ-sulfato-κ(2) O:O′]
title_short catena-Poly[[triaqua­(pyridine-κN)nickel(II)]-μ-sulfato-κ(2) O:O′]
title_sort catena-poly[[triaqua­(pyridine-κn)nickel(ii)]-μ-sulfato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971987/
https://www.ncbi.nlm.nih.gov/pubmed/21578675
http://dx.doi.org/10.1107/S1600536809049605
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