Cargando…

Bis(2,2′-bipyrid­yl)bromidocopper(II) bromide bromo­acetic acid hemihydrate

In the title compound, [CuBr(C(10)H(8)N(2))(2)]Br·BrCH(2)COOH·0.5H(2)O, the Cu(II) ion is coordinated by four N atoms [Cu—N = 1.985 (6)–2.125 (7) Å] from two 2,2′-bipyridine ligand mol­ecules and a bromide anion [Cu—Br = 2.471 (2) Å] in a distorted trigonal-bipyramidal geometry. Short centroid–centr...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Yaru, Sun, Junshan, Wang, Xinli
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971989/
https://www.ncbi.nlm.nih.gov/pubmed/21578660
http://dx.doi.org/10.1107/S1600536809048995
Descripción
Sumario:In the title compound, [CuBr(C(10)H(8)N(2))(2)]Br·BrCH(2)COOH·0.5H(2)O, the Cu(II) ion is coordinated by four N atoms [Cu—N = 1.985 (6)–2.125 (7) Å] from two 2,2′-bipyridine ligand mol­ecules and a bromide anion [Cu—Br = 2.471 (2) Å] in a distorted trigonal-bipyramidal geometry. Short centroid–centroid distances [3.762 (5) and 3.867 (5) Å] between the aromatic rings of neighbouring cations suggest the existence of π–π inter­actions. Inter­molecular O—H⋯Br hydrogen bonds and weak C—H⋯O and C—H⋯Br inter­actions consolidate the crystal packing.