Bis(2,2′-bipyrid­yl)bromidocopper(II) bromide bromo­acetic acid hemihydrate

In the title compound, [CuBr(C(10)H(8)N(2))(2)]Br·BrCH(2)COOH·0.5H(2)O, the Cu(II) ion is coordinated by four N atoms [Cu—N = 1.985 (6)–2.125 (7) Å] from two 2,2′-bipyridine ligand mol­ecules and a bromide anion [Cu—Br = 2.471 (2) Å] in a distorted trigonal-bipyramidal geometry. Short centroid–centr...

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Detalles Bibliográficos
Autores principales: Liu, Yaru, Sun, Junshan, Wang, Xinli
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971989/
https://www.ncbi.nlm.nih.gov/pubmed/21578660
http://dx.doi.org/10.1107/S1600536809048995
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author Liu, Yaru
Sun, Junshan
Wang, Xinli
author_facet Liu, Yaru
Sun, Junshan
Wang, Xinli
author_sort Liu, Yaru
collection PubMed
description In the title compound, [CuBr(C(10)H(8)N(2))(2)]Br·BrCH(2)COOH·0.5H(2)O, the Cu(II) ion is coordinated by four N atoms [Cu—N = 1.985 (6)–2.125 (7) Å] from two 2,2′-bipyridine ligand mol­ecules and a bromide anion [Cu—Br = 2.471 (2) Å] in a distorted trigonal-bipyramidal geometry. Short centroid–centroid distances [3.762 (5) and 3.867 (5) Å] between the aromatic rings of neighbouring cations suggest the existence of π–π inter­actions. Inter­molecular O—H⋯Br hydrogen bonds and weak C—H⋯O and C—H⋯Br inter­actions consolidate the crystal packing.
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spelling pubmed-29719892010-12-30 Bis(2,2′-bipyrid­yl)bromidocopper(II) bromide bromo­acetic acid hemihydrate Liu, Yaru Sun, Junshan Wang, Xinli Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuBr(C(10)H(8)N(2))(2)]Br·BrCH(2)COOH·0.5H(2)O, the Cu(II) ion is coordinated by four N atoms [Cu—N = 1.985 (6)–2.125 (7) Å] from two 2,2′-bipyridine ligand mol­ecules and a bromide anion [Cu—Br = 2.471 (2) Å] in a distorted trigonal-bipyramidal geometry. Short centroid–centroid distances [3.762 (5) and 3.867 (5) Å] between the aromatic rings of neighbouring cations suggest the existence of π–π inter­actions. Inter­molecular O—H⋯Br hydrogen bonds and weak C—H⋯O and C—H⋯Br inter­actions consolidate the crystal packing. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2971989/ /pubmed/21578660 http://dx.doi.org/10.1107/S1600536809048995 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yaru
Sun, Junshan
Wang, Xinli
Bis(2,2′-bipyrid­yl)bromidocopper(II) bromide bromo­acetic acid hemihydrate
title Bis(2,2′-bipyrid­yl)bromidocopper(II) bromide bromo­acetic acid hemihydrate
title_full Bis(2,2′-bipyrid­yl)bromidocopper(II) bromide bromo­acetic acid hemihydrate
title_fullStr Bis(2,2′-bipyrid­yl)bromidocopper(II) bromide bromo­acetic acid hemihydrate
title_full_unstemmed Bis(2,2′-bipyrid­yl)bromidocopper(II) bromide bromo­acetic acid hemihydrate
title_short Bis(2,2′-bipyrid­yl)bromidocopper(II) bromide bromo­acetic acid hemihydrate
title_sort bis(2,2′-bipyrid­yl)bromidocopper(ii) bromide bromo­acetic acid hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971989/
https://www.ncbi.nlm.nih.gov/pubmed/21578660
http://dx.doi.org/10.1107/S1600536809048995
work_keys_str_mv AT liuyaru bis22bipyridylbromidocopperiibromidebromoaceticacidhemihydrate
AT sunjunshan bis22bipyridylbromidocopperiibromidebromoaceticacidhemihydrate
AT wangxinli bis22bipyridylbromidocopperiibromidebromoaceticacidhemihydrate

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