(m-Phenyl­enedimethyl­ene)bis­(triphenyl­phospho­nium) bis­[chlorido(penta­fluoro­phen­yl)aurate(I)] dichloro­methane disolvate

The title compound, (C(44)H(38)P(2))[AuCl(C(6)F(5))](2)·2CH(2)Cl(2), crystallizes with a twofold rotation axis through the central benzene ring in the bis-phospho­nium dication. In the crystal, the dications and anions are ordered into columns running parallel to the c axis by contacts of the pro-yl...

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Detalles Bibliográficos
Autores principales: Strasser, Christoph E., Coetzee, Karolien, Cronje, Stephanie, Raubenheimer, Helgard G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971990/
https://www.ncbi.nlm.nih.gov/pubmed/21578550
http://dx.doi.org/10.1107/S1600536809045474
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author Strasser, Christoph E.
Coetzee, Karolien
Cronje, Stephanie
Raubenheimer, Helgard G.
author_facet Strasser, Christoph E.
Coetzee, Karolien
Cronje, Stephanie
Raubenheimer, Helgard G.
author_sort Strasser, Christoph E.
collection PubMed
description The title compound, (C(44)H(38)P(2))[AuCl(C(6)F(5))](2)·2CH(2)Cl(2), crystallizes with a twofold rotation axis through the central benzene ring in the bis-phospho­nium dication. In the crystal, the dications and anions are ordered into columns running parallel to the c axis by contacts of the pro-ylidic CH(2) groups with the Cl atom of one and an ortho-F atom of another anion. The space between the columns is occupied by CH(2)Cl(2) solvent mol­ecules.
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spelling pubmed-29719902010-12-30 (m-Phenyl­enedimethyl­ene)bis­(triphenyl­phospho­nium) bis­[chlorido(penta­fluoro­phen­yl)aurate(I)] dichloro­methane disolvate Strasser, Christoph E. Coetzee, Karolien Cronje, Stephanie Raubenheimer, Helgard G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(44)H(38)P(2))[AuCl(C(6)F(5))](2)·2CH(2)Cl(2), crystallizes with a twofold rotation axis through the central benzene ring in the bis-phospho­nium dication. In the crystal, the dications and anions are ordered into columns running parallel to the c axis by contacts of the pro-ylidic CH(2) groups with the Cl atom of one and an ortho-F atom of another anion. The space between the columns is occupied by CH(2)Cl(2) solvent mol­ecules. International Union of Crystallography 2009-11-04 /pmc/articles/PMC2971990/ /pubmed/21578550 http://dx.doi.org/10.1107/S1600536809045474 Text en © Strasser et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Strasser, Christoph E.
Coetzee, Karolien
Cronje, Stephanie
Raubenheimer, Helgard G.
(m-Phenyl­enedimethyl­ene)bis­(triphenyl­phospho­nium) bis­[chlorido(penta­fluoro­phen­yl)aurate(I)] dichloro­methane disolvate
title (m-Phenyl­enedimethyl­ene)bis­(triphenyl­phospho­nium) bis­[chlorido(penta­fluoro­phen­yl)aurate(I)] dichloro­methane disolvate
title_full (m-Phenyl­enedimethyl­ene)bis­(triphenyl­phospho­nium) bis­[chlorido(penta­fluoro­phen­yl)aurate(I)] dichloro­methane disolvate
title_fullStr (m-Phenyl­enedimethyl­ene)bis­(triphenyl­phospho­nium) bis­[chlorido(penta­fluoro­phen­yl)aurate(I)] dichloro­methane disolvate
title_full_unstemmed (m-Phenyl­enedimethyl­ene)bis­(triphenyl­phospho­nium) bis­[chlorido(penta­fluoro­phen­yl)aurate(I)] dichloro­methane disolvate
title_short (m-Phenyl­enedimethyl­ene)bis­(triphenyl­phospho­nium) bis­[chlorido(penta­fluoro­phen­yl)aurate(I)] dichloro­methane disolvate
title_sort (m-phenyl­enedimethyl­ene)bis­(triphenyl­phospho­nium) bis­[chlorido(penta­fluoro­phen­yl)aurate(i)] dichloro­methane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971990/
https://www.ncbi.nlm.nih.gov/pubmed/21578550
http://dx.doi.org/10.1107/S1600536809045474
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AT coetzeekarolien mphenylenedimethylenebistriphenylphosphoniumbischloridopentafluorophenylaurateidichloromethanedisolvate
AT cronjestephanie mphenylenedimethylenebistriphenylphosphoniumbischloridopentafluorophenylaurateidichloromethanedisolvate
AT raubenheimerhelgardg mphenylenedimethylenebistriphenylphosphoniumbischloridopentafluorophenylaurateidichloromethanedisolvate

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