Cargando…

Poly[bis­(4,4′-bipyridine)(μ(3)-4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ato)iron(II)]

In the polymeric title complex, [Fe(C(16)H(8)O(8))(C(10)H(8)N(2))(2)](n), the iron(II) cation is coordinated by four O atoms from three different 4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ate ligands and two N atoms from two 4,4′-bipyridine ligands in a distorted octa­hedral geometry. The 4,4′-dicarbo...

Descripción completa

Detalles Bibliográficos
Autores principales: Meng, Qun-Hui, Lai, Hui-Ling, Lu, Han, Luo, Yi-Fan, Zeng, Rong-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971993/
https://www.ncbi.nlm.nih.gov/pubmed/21578579
http://dx.doi.org/10.1107/S1600536809046273
_version_ 1782190718657232896
author Meng, Qun-Hui
Lai, Hui-Ling
Lu, Han
Luo, Yi-Fan
Zeng, Rong-Hua
author_facet Meng, Qun-Hui
Lai, Hui-Ling
Lu, Han
Luo, Yi-Fan
Zeng, Rong-Hua
author_sort Meng, Qun-Hui
collection PubMed
description In the polymeric title complex, [Fe(C(16)H(8)O(8))(C(10)H(8)N(2))(2)](n), the iron(II) cation is coordinated by four O atoms from three different 4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ate ligands and two N atoms from two 4,4′-bipyridine ligands in a distorted octa­hedral geometry. The 4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ate ligands bridge adjacent cations, forming chains parallel to the c axis. The chains are further connected by inter­molecular O—H⋯N hydrogen bonds, forming two-dimensional supra­molecular layers parallel to (010).
format Text
id pubmed-2971993
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29719932010-12-30 Poly[bis­(4,4′-bipyridine)(μ(3)-4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ato)iron(II)] Meng, Qun-Hui Lai, Hui-Ling Lu, Han Luo, Yi-Fan Zeng, Rong-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title complex, [Fe(C(16)H(8)O(8))(C(10)H(8)N(2))(2)](n), the iron(II) cation is coordinated by four O atoms from three different 4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ate ligands and two N atoms from two 4,4′-bipyridine ligands in a distorted octa­hedral geometry. The 4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ate ligands bridge adjacent cations, forming chains parallel to the c axis. The chains are further connected by inter­molecular O—H⋯N hydrogen bonds, forming two-dimensional supra­molecular layers parallel to (010). International Union of Crystallography 2009-11-07 /pmc/articles/PMC2971993/ /pubmed/21578579 http://dx.doi.org/10.1107/S1600536809046273 Text en © Meng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meng, Qun-Hui
Lai, Hui-Ling
Lu, Han
Luo, Yi-Fan
Zeng, Rong-Hua
Poly[bis­(4,4′-bipyridine)(μ(3)-4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ato)iron(II)]
title Poly[bis­(4,4′-bipyridine)(μ(3)-4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ato)iron(II)]
title_full Poly[bis­(4,4′-bipyridine)(μ(3)-4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ato)iron(II)]
title_fullStr Poly[bis­(4,4′-bipyridine)(μ(3)-4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ato)iron(II)]
title_full_unstemmed Poly[bis­(4,4′-bipyridine)(μ(3)-4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ato)iron(II)]
title_short Poly[bis­(4,4′-bipyridine)(μ(3)-4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ato)iron(II)]
title_sort poly[bis­(4,4′-bipyridine)(μ(3)-4,4′-dicarboxybiphenyl-3,3′-di­carboxyl­ato)iron(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971993/
https://www.ncbi.nlm.nih.gov/pubmed/21578579
http://dx.doi.org/10.1107/S1600536809046273
work_keys_str_mv AT mengqunhui polybis44bipyridinem344dicarboxybiphenyl33dicarboxylatoironii
AT laihuiling polybis44bipyridinem344dicarboxybiphenyl33dicarboxylatoironii
AT luhan polybis44bipyridinem344dicarboxybiphenyl33dicarboxylatoironii
AT luoyifan polybis44bipyridinem344dicarboxybiphenyl33dicarboxylatoironii
AT zengronghua polybis44bipyridinem344dicarboxybiphenyl33dicarboxylatoironii