Bis(2,2′-bipyridine)bis­{μ(3)-cis-N-(2-carboxyl­atophen­yl)-N′-[3-(dimethyl­amino)prop­yl]oxamidato(3−)}­bis(per­chlorato)­tetra­nickel(II) methanol disolvate

In the title methanol disolvate complex, [Ni(4)(C(14)H(16)N(3)O(4))(2)(ClO(4))(2)(C(10)H(8)N(2))(2)]·2CH(3)OH, the neutral tetra­nickel(II) system lies on a centre of inversion. The polyhedron around each Ni(II) atom is a square pyramid. The separations of the Ni atoms bridged by the oxamide and car...

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Detalles Bibliográficos
Autores principales: Tian, Chunliang, Gao, Zhongjun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971995/
https://www.ncbi.nlm.nih.gov/pubmed/21578696
http://dx.doi.org/10.1107/S160053680905017X
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author Tian, Chunliang
Gao, Zhongjun
author_facet Tian, Chunliang
Gao, Zhongjun
author_sort Tian, Chunliang
collection PubMed
description In the title methanol disolvate complex, [Ni(4)(C(14)H(16)N(3)O(4))(2)(ClO(4))(2)(C(10)H(8)N(2))(2)]·2CH(3)OH, the neutral tetra­nickel(II) system lies on a centre of inversion. The polyhedron around each Ni(II) atom is a square pyramid. The separations of the Ni atoms bridged by the oxamide and carboxyl groups are 5.227 (9) and 5.268 (6) Å, respectively. In the crystal structure, a two-dimensional supramolecular network structure involving O—H⋯O and C—H⋯O hydrogen bonding is observed.
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spelling pubmed-29719952010-12-30 Bis(2,2′-bipyridine)bis­{μ(3)-cis-N-(2-carboxyl­atophen­yl)-N′-[3-(dimethyl­amino)prop­yl]oxamidato(3−)}­bis(per­chlorato)­tetra­nickel(II) methanol disolvate Tian, Chunliang Gao, Zhongjun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title methanol disolvate complex, [Ni(4)(C(14)H(16)N(3)O(4))(2)(ClO(4))(2)(C(10)H(8)N(2))(2)]·2CH(3)OH, the neutral tetra­nickel(II) system lies on a centre of inversion. The polyhedron around each Ni(II) atom is a square pyramid. The separations of the Ni atoms bridged by the oxamide and carboxyl groups are 5.227 (9) and 5.268 (6) Å, respectively. In the crystal structure, a two-dimensional supramolecular network structure involving O—H⋯O and C—H⋯O hydrogen bonding is observed. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2971995/ /pubmed/21578696 http://dx.doi.org/10.1107/S160053680905017X Text en © Tian and Gao 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tian, Chunliang
Gao, Zhongjun
Bis(2,2′-bipyridine)bis­{μ(3)-cis-N-(2-carboxyl­atophen­yl)-N′-[3-(dimethyl­amino)prop­yl]oxamidato(3−)}­bis(per­chlorato)­tetra­nickel(II) methanol disolvate
title Bis(2,2′-bipyridine)bis­{μ(3)-cis-N-(2-carboxyl­atophen­yl)-N′-[3-(dimethyl­amino)prop­yl]oxamidato(3−)}­bis(per­chlorato)­tetra­nickel(II) methanol disolvate
title_full Bis(2,2′-bipyridine)bis­{μ(3)-cis-N-(2-carboxyl­atophen­yl)-N′-[3-(dimethyl­amino)prop­yl]oxamidato(3−)}­bis(per­chlorato)­tetra­nickel(II) methanol disolvate
title_fullStr Bis(2,2′-bipyridine)bis­{μ(3)-cis-N-(2-carboxyl­atophen­yl)-N′-[3-(dimethyl­amino)prop­yl]oxamidato(3−)}­bis(per­chlorato)­tetra­nickel(II) methanol disolvate
title_full_unstemmed Bis(2,2′-bipyridine)bis­{μ(3)-cis-N-(2-carboxyl­atophen­yl)-N′-[3-(dimethyl­amino)prop­yl]oxamidato(3−)}­bis(per­chlorato)­tetra­nickel(II) methanol disolvate
title_short Bis(2,2′-bipyridine)bis­{μ(3)-cis-N-(2-carboxyl­atophen­yl)-N′-[3-(dimethyl­amino)prop­yl]oxamidato(3−)}­bis(per­chlorato)­tetra­nickel(II) methanol disolvate
title_sort bis(2,2′-bipyridine)bis­{μ(3)-cis-n-(2-carboxyl­atophen­yl)-n′-[3-(dimethyl­amino)prop­yl]oxamidato(3−)}­bis(per­chlorato)­tetra­nickel(ii) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971995/
https://www.ncbi.nlm.nih.gov/pubmed/21578696
http://dx.doi.org/10.1107/S160053680905017X
work_keys_str_mv AT tianchunliang bis22bipyridinebism3cisn2carboxylatophenyln3dimethylaminopropyloxamidato3bisperchloratotetranickeliimethanoldisolvate
AT gaozhongjun bis22bipyridinebism3cisn2carboxylatophenyln3dimethylaminopropyloxamidato3bisperchloratotetranickeliimethanoldisolvate

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