9,9-Dimethyl-12-phenyl-8,9-dihydro-12H-benzo[a]xanthen-11(10H)-one

The title compound, C(25)H(22)O(2), was synthesized via the three-component coupling of benzaldehyde, 2-naphthol and 5,5-dimethyl­cyclo­hexane-1,3-dione. In the crystal structure, centrosymmetrically related mol­ecules are linked into dimers by pairs of inter­molecular C—H⋯O hydrogen bonds. The dime...

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Detalles Bibliográficos
Autores principales: Zhang, Yong, Zang, Hong-Jun, Cheng, Bo-Wen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971999/
https://www.ncbi.nlm.nih.gov/pubmed/21578757
http://dx.doi.org/10.1107/S1600536809046157
Descripción
Sumario:The title compound, C(25)H(22)O(2), was synthesized via the three-component coupling of benzaldehyde, 2-naphthol and 5,5-dimethyl­cyclo­hexane-1,3-dione. In the crystal structure, centrosymmetrically related mol­ecules are linked into dimers by pairs of inter­molecular C—H⋯O hydrogen bonds. The dimers are further connected into a three-dimensional network by π–π aromatic stacking inter­actions involving the naphthalene ring system, with centroid–centroid separations of 3.695 (7) Å.

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