Cargando…
[4-Carboxyimidazole-5-carboxylato(2–)-κ(2) N (1),O (5)](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) monohydrate
The 4-carboxyimidazole-5-carboxylate(2−) dianion in the title compound, [Ni(C(5)H(2)N(2)O(4))(C(16)H(36)N(4))]·H(2)O, N,O′-chelates to the Ni(II) atom, which shows an octahedral coordination. The macrocycle folds itself around the metal atom and binds to it through four secondary nitrogen atoms;...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972002/ https://www.ncbi.nlm.nih.gov/pubmed/21578593 http://dx.doi.org/10.1107/S1600536809046145 |
| _version_ | 1782190720857145344 |
|---|---|
| author | Ou, Guang-Chuan Zhou, Qiang Ng, Seik Weng |
| author_facet | Ou, Guang-Chuan Zhou, Qiang Ng, Seik Weng |
| author_sort | Ou, Guang-Chuan |
| collection | PubMed |
| description | The 4-carboxyimidazole-5-carboxylate(2−) dianion in the title compound, [Ni(C(5)H(2)N(2)O(4))(C(16)H(36)N(4))]·H(2)O, N,O′-chelates to the Ni(II) atom, which shows an octahedral coordination. The macrocycle folds itself around the metal atom and binds to it through four secondary nitrogen atoms; adjacent molecules are linked by N—H⋯O hydrogen bonds into a linear chain. The water molecule is disordered over two positions. |
| format | Text |
| id | pubmed-2972002 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29720022010-12-30 [4-Carboxyimidazole-5-carboxylato(2–)-κ(2) N (1),O (5)](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) monohydrate Ou, Guang-Chuan Zhou, Qiang Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The 4-carboxyimidazole-5-carboxylate(2−) dianion in the title compound, [Ni(C(5)H(2)N(2)O(4))(C(16)H(36)N(4))]·H(2)O, N,O′-chelates to the Ni(II) atom, which shows an octahedral coordination. The macrocycle folds itself around the metal atom and binds to it through four secondary nitrogen atoms; adjacent molecules are linked by N—H⋯O hydrogen bonds into a linear chain. The water molecule is disordered over two positions. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2972002/ /pubmed/21578593 http://dx.doi.org/10.1107/S1600536809046145 Text en © Ou et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ou, Guang-Chuan Zhou, Qiang Ng, Seik Weng [4-Carboxyimidazole-5-carboxylato(2–)-κ(2) N (1),O (5)](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)nickel(II) monohydrate |
| title | [4-Carboxyimidazole-5-carboxylato(2–)-κ(2)
N
(1),O
(5)](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) monohydrate |
| title_full | [4-Carboxyimidazole-5-carboxylato(2–)-κ(2)
N
(1),O
(5)](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) monohydrate |
| title_fullStr | [4-Carboxyimidazole-5-carboxylato(2–)-κ(2)
N
(1),O
(5)](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) monohydrate |
| title_full_unstemmed | [4-Carboxyimidazole-5-carboxylato(2–)-κ(2)
N
(1),O
(5)](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) monohydrate |
| title_short | [4-Carboxyimidazole-5-carboxylato(2–)-κ(2)
N
(1),O
(5)](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N,N′,N′′,N′′′)nickel(II) monohydrate |
| title_sort | [4-carboxyimidazole-5-carboxylato(2–)-κ(2)
n
(1),o
(5)](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
n,n′,n′′,n′′′)nickel(ii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972002/ https://www.ncbi.nlm.nih.gov/pubmed/21578593 http://dx.doi.org/10.1107/S1600536809046145 |
| work_keys_str_mv | AT ouguangchuan 4carboxyimidazole5carboxylato2k2n1o5557121214hexamethyl14811tetraazacyclotetradecanek4nnnnnickeliimonohydrate AT zhouqiang 4carboxyimidazole5carboxylato2k2n1o5557121214hexamethyl14811tetraazacyclotetradecanek4nnnnnickeliimonohydrate AT ngseikweng 4carboxyimidazole5carboxylato2k2n1o5557121214hexamethyl14811tetraazacyclotetradecanek4nnnnnickeliimonohydrate |