6-Chloro-N (2),N (4)-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethyl­formamide monosolvate

The title compound, C(17)H(16)ClN(5)·C(3)H(7)NO, was prepared by reaction of p-toluidine with 2,4,6-trichloro-1,3,5-triazine at room temperature. The dihedral angles between the triazine ring and the pendant rings are 3.61 (12) and 53.11 (12)°. An intra­molecular C—H⋯N inter­action occurs. The packi...

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Detalles Bibliográficos
Autores principales: Jian, Fangfang, Xiao, Hailian, Wei, Yongxiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972005/
https://www.ncbi.nlm.nih.gov/pubmed/21578920
http://dx.doi.org/10.1107/S1600536809049885
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author Jian, Fangfang
Xiao, Hailian
Wei, Yongxiang
author_facet Jian, Fangfang
Xiao, Hailian
Wei, Yongxiang
author_sort Jian, Fangfang
collection PubMed
description The title compound, C(17)H(16)ClN(5)·C(3)H(7)NO, was prepared by reaction of p-toluidine with 2,4,6-trichloro-1,3,5-triazine at room temperature. The dihedral angles between the triazine ring and the pendant rings are 3.61 (12) and 53.11 (12)°. An intra­molecular C—H⋯N inter­action occurs. The packing is stabilized by N—H⋯N and N—H⋯O hydrogen bonds and C—H⋯π and π–π [centroid–centroid distance = 3.763 (1) Å] inter­actions.
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spelling pubmed-29720052010-12-30 6-Chloro-N (2),N (4)-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethyl­formamide monosolvate Jian, Fangfang Xiao, Hailian Wei, Yongxiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(16)ClN(5)·C(3)H(7)NO, was prepared by reaction of p-toluidine with 2,4,6-trichloro-1,3,5-triazine at room temperature. The dihedral angles between the triazine ring and the pendant rings are 3.61 (12) and 53.11 (12)°. An intra­molecular C—H⋯N inter­action occurs. The packing is stabilized by N—H⋯N and N—H⋯O hydrogen bonds and C—H⋯π and π–π [centroid–centroid distance = 3.763 (1) Å] inter­actions. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2972005/ /pubmed/21578920 http://dx.doi.org/10.1107/S1600536809049885 Text en © Jian et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jian, Fangfang
Xiao, Hailian
Wei, Yongxiang
6-Chloro-N (2),N (4)-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethyl­formamide monosolvate
title 6-Chloro-N (2),N (4)-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethyl­formamide monosolvate
title_full 6-Chloro-N (2),N (4)-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethyl­formamide monosolvate
title_fullStr 6-Chloro-N (2),N (4)-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethyl­formamide monosolvate
title_full_unstemmed 6-Chloro-N (2),N (4)-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethyl­formamide monosolvate
title_short 6-Chloro-N (2),N (4)-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethyl­formamide monosolvate
title_sort 6-chloro-n (2),n (4)-di-p-tolyl-1,3,5-triazine-2,4-diamine dimethyl­formamide monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972005/
https://www.ncbi.nlm.nih.gov/pubmed/21578920
http://dx.doi.org/10.1107/S1600536809049885
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