Tris(ethyl­enediamine)zinc(II) hexa­fluorido­silicate

The title compound, [Zn(C(2)H(8)N(2))(3)](SiF(6)), was synthesized ionothermally using choline chloride–imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octa­hedral geometry. The...

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Detalles Bibliográficos
Autores principales: Li, Yang, Shi, Qi, Slawin, Alexandra M. Z., Woollins, J. Derek, Dong, Jinxiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972015/
https://www.ncbi.nlm.nih.gov/pubmed/21578568
http://dx.doi.org/10.1107/S1600536809045693
Descripción
Sumario:The title compound, [Zn(C(2)H(8)N(2))(3)](SiF(6)), was synthesized ionothermally using choline chloride–imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octa­hedral geometry. The Zn(II) ion is coordinated by six N atoms from three ethyl­enediamine mol­ecules. The crystal structure displays weak hydrogen bonding between [SiF(6)](2−) anions and the ethyl­enediamine NH hydrogen atoms.

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