Tris(ethyl­enediamine)zinc(II) hexa­fluorido­silicate

The title compound, [Zn(C(2)H(8)N(2))(3)](SiF(6)), was synthesized ionothermally using choline chloride–imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octa­hedral geometry. The...

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Detalles Bibliográficos
Autores principales: Li, Yang, Shi, Qi, Slawin, Alexandra M. Z., Woollins, J. Derek, Dong, Jinxiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972015/
https://www.ncbi.nlm.nih.gov/pubmed/21578568
http://dx.doi.org/10.1107/S1600536809045693
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author Li, Yang
Shi, Qi
Slawin, Alexandra M. Z.
Woollins, J. Derek
Dong, Jinxiang
author_facet Li, Yang
Shi, Qi
Slawin, Alexandra M. Z.
Woollins, J. Derek
Dong, Jinxiang
author_sort Li, Yang
collection PubMed
description The title compound, [Zn(C(2)H(8)N(2))(3)](SiF(6)), was synthesized ionothermally using choline chloride–imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octa­hedral geometry. The Zn(II) ion is coordinated by six N atoms from three ethyl­enediamine mol­ecules. The crystal structure displays weak hydrogen bonding between [SiF(6)](2−) anions and the ethyl­enediamine NH hydrogen atoms.
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spelling pubmed-29720152010-12-30 Tris(ethyl­enediamine)zinc(II) hexa­fluorido­silicate Li, Yang Shi, Qi Slawin, Alexandra M. Z. Woollins, J. Derek Dong, Jinxiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(2)H(8)N(2))(3)](SiF(6)), was synthesized ionothermally using choline chloride–imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octa­hedral geometry. The Zn(II) ion is coordinated by six N atoms from three ethyl­enediamine mol­ecules. The crystal structure displays weak hydrogen bonding between [SiF(6)](2−) anions and the ethyl­enediamine NH hydrogen atoms. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2972015/ /pubmed/21578568 http://dx.doi.org/10.1107/S1600536809045693 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Yang
Shi, Qi
Slawin, Alexandra M. Z.
Woollins, J. Derek
Dong, Jinxiang
Tris(ethyl­enediamine)zinc(II) hexa­fluorido­silicate
title Tris(ethyl­enediamine)zinc(II) hexa­fluorido­silicate
title_full Tris(ethyl­enediamine)zinc(II) hexa­fluorido­silicate
title_fullStr Tris(ethyl­enediamine)zinc(II) hexa­fluorido­silicate
title_full_unstemmed Tris(ethyl­enediamine)zinc(II) hexa­fluorido­silicate
title_short Tris(ethyl­enediamine)zinc(II) hexa­fluorido­silicate
title_sort tris(ethyl­enediamine)zinc(ii) hexa­fluorido­silicate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972015/
https://www.ncbi.nlm.nih.gov/pubmed/21578568
http://dx.doi.org/10.1107/S1600536809045693
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AT slawinalexandramz trisethylenediaminezinciihexafluoridosilicate
AT woollinsjderek trisethylenediaminezinciihexafluoridosilicate
AT dongjinxiang trisethylenediaminezinciihexafluoridosilicate

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