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Poly[1,4-bis(4-pyridylmethyl)piperazinediium [[tetraaquacobaltate(II)]-μ-pyromellitato-κ(2) O (1):O (4)] dihydrate]
In the title compound, {(C(16)H(22)N(4))[Co(C(10)H(2)O(8))(H(2)O)(4)]·2H(2)O}(n), the octahedrally coordinated Co(II) atom is situated on an inversion center and possesses four aqua ligands. The Co atoms are linked into an anionic coordination polymer chain by bis-monodentate pyromellitate ligands....
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972020/ https://www.ncbi.nlm.nih.gov/pubmed/21578710 http://dx.doi.org/10.1107/S1600536809051101 |
| _version_ | 1782190725183569920 |
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| author | Sposato, Laura K. LaDuca, Robert L. |
| author_facet | Sposato, Laura K. LaDuca, Robert L. |
| author_sort | Sposato, Laura K. |
| collection | PubMed |
| description | In the title compound, {(C(16)H(22)N(4))[Co(C(10)H(2)O(8))(H(2)O)(4)]·2H(2)O}(n), the octahedrally coordinated Co(II) atom is situated on an inversion center and possesses four aqua ligands. The Co atoms are linked into an anionic coordination polymer chain by bis-monodentate pyromellitate ligands. The chain motifs are connected into a supramolecular layer by hydrogen bonding mediated by uncoordinated water molecules. Charge balance is provided by doubly protonated bis(4-pyridylmethyl)piperazine units, which are anchored to the coordination polymer chain motifs by N—H⋯O hydrogen bonding. |
| format | Text |
| id | pubmed-2972020 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29720202010-12-30 Poly[1,4-bis(4-pyridylmethyl)piperazinediium [[tetraaquacobaltate(II)]-μ-pyromellitato-κ(2) O (1):O (4)] dihydrate] Sposato, Laura K. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {(C(16)H(22)N(4))[Co(C(10)H(2)O(8))(H(2)O)(4)]·2H(2)O}(n), the octahedrally coordinated Co(II) atom is situated on an inversion center and possesses four aqua ligands. The Co atoms are linked into an anionic coordination polymer chain by bis-monodentate pyromellitate ligands. The chain motifs are connected into a supramolecular layer by hydrogen bonding mediated by uncoordinated water molecules. Charge balance is provided by doubly protonated bis(4-pyridylmethyl)piperazine units, which are anchored to the coordination polymer chain motifs by N—H⋯O hydrogen bonding. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2972020/ /pubmed/21578710 http://dx.doi.org/10.1107/S1600536809051101 Text en © Sposato and LaDuca 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Sposato, Laura K. LaDuca, Robert L. Poly[1,4-bis(4-pyridylmethyl)piperazinediium [[tetraaquacobaltate(II)]-μ-pyromellitato-κ(2) O (1):O (4)] dihydrate] |
| title | Poly[1,4-bis(4-pyridylmethyl)piperazinediium [[tetraaquacobaltate(II)]-μ-pyromellitato-κ(2)
O
(1):O
(4)] dihydrate] |
| title_full | Poly[1,4-bis(4-pyridylmethyl)piperazinediium [[tetraaquacobaltate(II)]-μ-pyromellitato-κ(2)
O
(1):O
(4)] dihydrate] |
| title_fullStr | Poly[1,4-bis(4-pyridylmethyl)piperazinediium [[tetraaquacobaltate(II)]-μ-pyromellitato-κ(2)
O
(1):O
(4)] dihydrate] |
| title_full_unstemmed | Poly[1,4-bis(4-pyridylmethyl)piperazinediium [[tetraaquacobaltate(II)]-μ-pyromellitato-κ(2)
O
(1):O
(4)] dihydrate] |
| title_short | Poly[1,4-bis(4-pyridylmethyl)piperazinediium [[tetraaquacobaltate(II)]-μ-pyromellitato-κ(2)
O
(1):O
(4)] dihydrate] |
| title_sort | poly[1,4-bis(4-pyridylmethyl)piperazinediium [[tetraaquacobaltate(ii)]-μ-pyromellitato-κ(2)
o
(1):o
(4)] dihydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972020/ https://www.ncbi.nlm.nih.gov/pubmed/21578710 http://dx.doi.org/10.1107/S1600536809051101 |
| work_keys_str_mv | AT sposatolaurak poly14bis4pyridylmethylpiperazinediiumtetraaquacobaltateiimpyromellitatok2o1o4dihydrate AT laducarobertl poly14bis4pyridylmethylpiperazinediiumtetraaquacobaltateiimpyromellitatok2o1o4dihydrate |