Tetra-μ-benzoato-bis­{[trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene]zinc(II)}

The paddle-wheel-type centrosymmetric dinuclear title complex, [Zn(2)(C(7)H(5)O(2))(4)(C(12)H(10)N(2))(2)], contains four bridging benzoate groups and two terminal trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene (L) ligands. The inversion center is located between the two Zn(II) atoms. The octa­hedral...

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Detalles Bibliográficos
Autores principales: Song, Young Joo, Lee, Soo-Won, Jang, Kyung Hwan, Kim, Cheal, Kim, Youngmee
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972024/
https://www.ncbi.nlm.nih.gov/pubmed/21578547
http://dx.doi.org/10.1107/S1600536809045048
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author Song, Young Joo
Lee, Soo-Won
Jang, Kyung Hwan
Kim, Cheal
Kim, Youngmee
author_facet Song, Young Joo
Lee, Soo-Won
Jang, Kyung Hwan
Kim, Cheal
Kim, Youngmee
author_sort Song, Young Joo
collection PubMed
description The paddle-wheel-type centrosymmetric dinuclear title complex, [Zn(2)(C(7)H(5)O(2))(4)(C(12)H(10)N(2))(2)], contains four bridging benzoate groups and two terminal trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene (L) ligands. The inversion center is located between the two Zn(II) atoms. The octa­hedral coordination around the Zn(II) atom, with four O atoms in the equatorial plane, is completed by an N atom of the L mol­ecule [Zn—N = 2.0198 (15) Å] and by the second Zn(II) atom [Zn⋯Zn = 2.971 (8) Å]. The Zn(II) atom is 0.372 Å out of the plane of the four coordinating O atoms.
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spelling pubmed-29720242010-12-30 Tetra-μ-benzoato-bis­{[trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene]zinc(II)} Song, Young Joo Lee, Soo-Won Jang, Kyung Hwan Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The paddle-wheel-type centrosymmetric dinuclear title complex, [Zn(2)(C(7)H(5)O(2))(4)(C(12)H(10)N(2))(2)], contains four bridging benzoate groups and two terminal trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene (L) ligands. The inversion center is located between the two Zn(II) atoms. The octa­hedral coordination around the Zn(II) atom, with four O atoms in the equatorial plane, is completed by an N atom of the L mol­ecule [Zn—N = 2.0198 (15) Å] and by the second Zn(II) atom [Zn⋯Zn = 2.971 (8) Å]. The Zn(II) atom is 0.372 Å out of the plane of the four coordinating O atoms. International Union of Crystallography 2009-11-04 /pmc/articles/PMC2972024/ /pubmed/21578547 http://dx.doi.org/10.1107/S1600536809045048 Text en © Song et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Young Joo
Lee, Soo-Won
Jang, Kyung Hwan
Kim, Cheal
Kim, Youngmee
Tetra-μ-benzoato-bis­{[trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene]zinc(II)}
title Tetra-μ-benzoato-bis­{[trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene]zinc(II)}
title_full Tetra-μ-benzoato-bis­{[trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene]zinc(II)}
title_fullStr Tetra-μ-benzoato-bis­{[trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene]zinc(II)}
title_full_unstemmed Tetra-μ-benzoato-bis­{[trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene]zinc(II)}
title_short Tetra-μ-benzoato-bis­{[trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene]zinc(II)}
title_sort tetra-μ-benzoato-bis­{[trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene]zinc(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972024/
https://www.ncbi.nlm.nih.gov/pubmed/21578547
http://dx.doi.org/10.1107/S1600536809045048
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AT jangkyunghwan tetrambenzoatobistrans12pyridyl24pyridylethylenezincii
AT kimcheal tetrambenzoatobistrans12pyridyl24pyridylethylenezincii
AT kimyoungmee tetrambenzoatobistrans12pyridyl24pyridylethylenezincii

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