(1R,3S)-Methyl 2-benzyl-6,7-dimeth­oxy-1-phenyl-1,2,3,4-tetra­hydro­isoquinoline-3-carboxyl­ate

In the title compound, C(26)H(27)NO(4), a precursor to novel chiral catalysts, the N-containing six-membered ring assumes a half-boat conformation. Various C—H⋯π interactions and intermolecular short contacts (C⋯H = 2.81–2.90 Å) link the mol­ecules together in the crystal structure.

Detalles Bibliográficos
Autores principales: Naicker, Tricia, McKay, Michael, Govender, Thavendran, Kruger, Hendrik G., Maguire, Glenn E. M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972025/
https://www.ncbi.nlm.nih.gov/pubmed/21578971
http://dx.doi.org/10.1107/S1600536809050521
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author Naicker, Tricia
McKay, Michael
Govender, Thavendran
Kruger, Hendrik G.
Maguire, Glenn E. M.
author_facet Naicker, Tricia
McKay, Michael
Govender, Thavendran
Kruger, Hendrik G.
Maguire, Glenn E. M.
author_sort Naicker, Tricia
collection PubMed
description In the title compound, C(26)H(27)NO(4), a precursor to novel chiral catalysts, the N-containing six-membered ring assumes a half-boat conformation. Various C—H⋯π interactions and intermolecular short contacts (C⋯H = 2.81–2.90 Å) link the mol­ecules together in the crystal structure.
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spelling pubmed-29720252010-12-30 (1R,3S)-Methyl 2-benzyl-6,7-dimeth­oxy-1-phenyl-1,2,3,4-tetra­hydro­isoquinoline-3-carboxyl­ate Naicker, Tricia McKay, Michael Govender, Thavendran Kruger, Hendrik G. Maguire, Glenn E. M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(27)NO(4), a precursor to novel chiral catalysts, the N-containing six-membered ring assumes a half-boat conformation. Various C—H⋯π interactions and intermolecular short contacts (C⋯H = 2.81–2.90 Å) link the mol­ecules together in the crystal structure. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2972025/ /pubmed/21578971 http://dx.doi.org/10.1107/S1600536809050521 Text en © Naicker et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Naicker, Tricia
McKay, Michael
Govender, Thavendran
Kruger, Hendrik G.
Maguire, Glenn E. M.
(1R,3S)-Methyl 2-benzyl-6,7-dimeth­oxy-1-phenyl-1,2,3,4-tetra­hydro­isoquinoline-3-carboxyl­ate
title (1R,3S)-Methyl 2-benzyl-6,7-dimeth­oxy-1-phenyl-1,2,3,4-tetra­hydro­isoquinoline-3-carboxyl­ate
title_full (1R,3S)-Methyl 2-benzyl-6,7-dimeth­oxy-1-phenyl-1,2,3,4-tetra­hydro­isoquinoline-3-carboxyl­ate
title_fullStr (1R,3S)-Methyl 2-benzyl-6,7-dimeth­oxy-1-phenyl-1,2,3,4-tetra­hydro­isoquinoline-3-carboxyl­ate
title_full_unstemmed (1R,3S)-Methyl 2-benzyl-6,7-dimeth­oxy-1-phenyl-1,2,3,4-tetra­hydro­isoquinoline-3-carboxyl­ate
title_short (1R,3S)-Methyl 2-benzyl-6,7-dimeth­oxy-1-phenyl-1,2,3,4-tetra­hydro­isoquinoline-3-carboxyl­ate
title_sort (1r,3s)-methyl 2-benzyl-6,7-dimeth­oxy-1-phenyl-1,2,3,4-tetra­hydro­isoquinoline-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972025/
https://www.ncbi.nlm.nih.gov/pubmed/21578971
http://dx.doi.org/10.1107/S1600536809050521
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