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N-(2,5-Dichlorophenyl)maleamic acid
The asymmetric unit of the title compound, C(10)H(7)Cl(2)NO(3), contains two independent molecules. The molecular conformation of each maleamic unit is stabilized by an intramolecular O—H⋯O(carbonyl) hydrogen bond owing to the anti disposition of the participating entities. The mean planes throu...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972031/ https://www.ncbi.nlm.nih.gov/pubmed/21578844 http://dx.doi.org/10.1107/S1600536809048715 |
Sumario: | The asymmetric unit of the title compound, C(10)H(7)Cl(2)NO(3), contains two independent molecules. The molecular conformation of each maleamic unit is stabilized by an intramolecular O—H⋯O(carbonyl) hydrogen bond owing to the anti disposition of the participating entities. The mean planes through the benzene ring and the amido group are inclined at angles of 45.7 (1) and 40.8 (1)° in the two molecules. In the crystal, the independent molecules self-associate via N—H⋯O hydrogen bonds into zigzag ribbons propagating along the a axis. The ribbons are weakly coupled by C—H⋯π and C—H⋯O interactions. |
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