N-(2,5-Dichloro­phen­yl)maleamic acid

The asymmetric unit of the title compound, C(10)H(7)Cl(2)NO(3), contains two independent mol­ecules. The mol­ecular conformation of each maleamic unit is stabilized by an intra­molecular O—H⋯O(carbon­yl) hydrogen bond owing to the anti disposition of the participating entities. The mean planes throu...

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Detalles Bibliográficos
Autores principales: Shakuntala, K., Gowda, B. Thimme, Tokarčík, Miroslav, Kožíšek, Jozef
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972031/
https://www.ncbi.nlm.nih.gov/pubmed/21578844
http://dx.doi.org/10.1107/S1600536809048715
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author Shakuntala, K.
Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
author_facet Shakuntala, K.
Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
author_sort Shakuntala, K.
collection PubMed
description The asymmetric unit of the title compound, C(10)H(7)Cl(2)NO(3), contains two independent mol­ecules. The mol­ecular conformation of each maleamic unit is stabilized by an intra­molecular O—H⋯O(carbon­yl) hydrogen bond owing to the anti disposition of the participating entities. The mean planes through the benzene ring and the amido group are inclined at angles of 45.7 (1) and 40.8 (1)° in the two mol­ecules. In the crystal, the independent mol­ecules self-associate via N—H⋯O hydrogen bonds into zigzag ribbons propagating along the a axis. The ribbons are weakly coupled by C—H⋯π and C—H⋯O inter­actions.
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spelling pubmed-29720312010-12-30 N-(2,5-Dichloro­phen­yl)maleamic acid Shakuntala, K. Gowda, B. Thimme Tokarčík, Miroslav Kožíšek, Jozef Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(7)Cl(2)NO(3), contains two independent mol­ecules. The mol­ecular conformation of each maleamic unit is stabilized by an intra­molecular O—H⋯O(carbon­yl) hydrogen bond owing to the anti disposition of the participating entities. The mean planes through the benzene ring and the amido group are inclined at angles of 45.7 (1) and 40.8 (1)° in the two mol­ecules. In the crystal, the independent mol­ecules self-associate via N—H⋯O hydrogen bonds into zigzag ribbons propagating along the a axis. The ribbons are weakly coupled by C—H⋯π and C—H⋯O inter­actions. International Union of Crystallography 2009-11-18 /pmc/articles/PMC2972031/ /pubmed/21578844 http://dx.doi.org/10.1107/S1600536809048715 Text en © Shakuntala et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shakuntala, K.
Gowda, B. Thimme
Tokarčík, Miroslav
Kožíšek, Jozef
N-(2,5-Dichloro­phen­yl)maleamic acid
title N-(2,5-Dichloro­phen­yl)maleamic acid
title_full N-(2,5-Dichloro­phen­yl)maleamic acid
title_fullStr N-(2,5-Dichloro­phen­yl)maleamic acid
title_full_unstemmed N-(2,5-Dichloro­phen­yl)maleamic acid
title_short N-(2,5-Dichloro­phen­yl)maleamic acid
title_sort n-(2,5-dichloro­phen­yl)maleamic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972031/
https://www.ncbi.nlm.nih.gov/pubmed/21578844
http://dx.doi.org/10.1107/S1600536809048715
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AT gowdabthimme n25dichlorophenylmaleamicacid
AT tokarcikmiroslav n25dichlorophenylmaleamicacid
AT kozisekjozef n25dichlorophenylmaleamicacid

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