{2,2′-[5-Bromo­pyridine-2,3-diylbis(nitrilo­methyl­idyne)]diphenolato}chlorido(dimethyl­formamide)manganese(III)

In the title complex, [Mn(C(19)H(12)BrN(3)O(2))Cl(C(3)H(7)NO)], the Mn(III) ion is coordinated by two N and two O atoms from the tetra­dentate Schiff base ligand, one O atom from the dimethyl­formamide ligand and a Cl anion in a distorted octa­hedral geometry. In the crystal structure, weak inter­mo...

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Detalles Bibliográficos
Autores principales: Xie, Hai, Meng, Shuangming, Zhu, Yongjun, Bai, Peiwan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972037/
https://www.ncbi.nlm.nih.gov/pubmed/21578679
http://dx.doi.org/10.1107/S1600536809049484
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author Xie, Hai
Meng, Shuangming
Zhu, Yongjun
Bai, Peiwan
author_facet Xie, Hai
Meng, Shuangming
Zhu, Yongjun
Bai, Peiwan
author_sort Xie, Hai
collection PubMed
description In the title complex, [Mn(C(19)H(12)BrN(3)O(2))Cl(C(3)H(7)NO)], the Mn(III) ion is coordinated by two N and two O atoms from the tetra­dentate Schiff base ligand, one O atom from the dimethyl­formamide ligand and a Cl anion in a distorted octa­hedral geometry. In the crystal structure, weak inter­molecular C—H⋯Cl hydrogen bonds link the mol­ecules into centrosymmetric dimers with a short distance of 3.878 (3) Å between the centroids of the aromatic rings.
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spelling pubmed-29720372010-12-30 {2,2′-[5-Bromo­pyridine-2,3-diylbis(nitrilo­methyl­idyne)]diphenolato}chlorido(dimethyl­formamide)manganese(III) Xie, Hai Meng, Shuangming Zhu, Yongjun Bai, Peiwan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(19)H(12)BrN(3)O(2))Cl(C(3)H(7)NO)], the Mn(III) ion is coordinated by two N and two O atoms from the tetra­dentate Schiff base ligand, one O atom from the dimethyl­formamide ligand and a Cl anion in a distorted octa­hedral geometry. In the crystal structure, weak inter­molecular C—H⋯Cl hydrogen bonds link the mol­ecules into centrosymmetric dimers with a short distance of 3.878 (3) Å between the centroids of the aromatic rings. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2972037/ /pubmed/21578679 http://dx.doi.org/10.1107/S1600536809049484 Text en © Xie et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xie, Hai
Meng, Shuangming
Zhu, Yongjun
Bai, Peiwan
{2,2′-[5-Bromo­pyridine-2,3-diylbis(nitrilo­methyl­idyne)]diphenolato}chlorido(dimethyl­formamide)manganese(III)
title {2,2′-[5-Bromo­pyridine-2,3-diylbis(nitrilo­methyl­idyne)]diphenolato}chlorido(dimethyl­formamide)manganese(III)
title_full {2,2′-[5-Bromo­pyridine-2,3-diylbis(nitrilo­methyl­idyne)]diphenolato}chlorido(dimethyl­formamide)manganese(III)
title_fullStr {2,2′-[5-Bromo­pyridine-2,3-diylbis(nitrilo­methyl­idyne)]diphenolato}chlorido(dimethyl­formamide)manganese(III)
title_full_unstemmed {2,2′-[5-Bromo­pyridine-2,3-diylbis(nitrilo­methyl­idyne)]diphenolato}chlorido(dimethyl­formamide)manganese(III)
title_short {2,2′-[5-Bromo­pyridine-2,3-diylbis(nitrilo­methyl­idyne)]diphenolato}chlorido(dimethyl­formamide)manganese(III)
title_sort {2,2′-[5-bromo­pyridine-2,3-diylbis(nitrilo­methyl­idyne)]diphenolato}chlorido(dimethyl­formamide)manganese(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972037/
https://www.ncbi.nlm.nih.gov/pubmed/21578679
http://dx.doi.org/10.1107/S1600536809049484
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AT baipeiwan 225bromopyridine23diylbisnitrilomethylidynediphenolatochloridodimethylformamidemanganeseiii

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